catena-Poly[[[aqua(1,10-phenanthroline)manganese(II)]-μ-adamantane-1,3-dicarboxylato] monohydrate]

catena-Poly[[[aqua(1,10-phenanthroline)manganese(II)]-μ-adamantane-1,3-dicarboxylato] monohydrate]

In the title coordination polymer, {[Mn(C12H14O4)(C12H8N2)(H2O)]·H2O}n, the MnII atom has a highly distorted cis-MnN2O4 octahedral geometry arising from its coordination by a bidentate phenanthroline ligand, a water molecule and monodentate and bidentate adamantane-1,3-dicarboxylate dia...

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Main Authors: Jian-Qiang Liu, Yun-Sheng Huang
Format: Article
Language:English
Published: International Union of Crystallography 2011-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811041900
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spelling doaj-dc698098dc0e41678ad265b7c0d810662020-11-25T02:07:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711m1541m154210.1107/S1600536811041900catena-Poly[[[aqua(1,10-phenanthroline)manganese(II)]-μ-adamantane-1,3-dicarboxylato] monohydrate]Jian-Qiang LiuYun-Sheng HuangIn the title coordination polymer, {[Mn(C12H14O4)(C12H8N2)(H2O)]·H2O}n, the MnII atom has a highly distorted cis-MnN2O4 octahedral geometry arising from its coordination by a bidentate phenanthroline ligand, a water molecule and monodentate and bidentate adamantane-1,3-dicarboxylate dianions. The bridging dianion leads to [001] chains in the crystal. The chains are linked by O—H...O hydrogen bonds, involving both the coordinated and uncoordinated water molecules, thereby forming a two-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536811041900
collection DOAJ
language English
format Article
sources DOAJ
author Jian-Qiang Liu
Yun-Sheng Huang
spellingShingle Jian-Qiang Liu
Yun-Sheng Huang
catena-Poly[[[aqua(1,10-phenanthroline)manganese(II)]-μ-adamantane-1,3-dicarboxylato] monohydrate]
Acta Crystallographica Section E
author_facet Jian-Qiang Liu
Yun-Sheng Huang
author_sort Jian-Qiang Liu
title catena-Poly[[[aqua(1,10-phenanthroline)manganese(II)]-μ-adamantane-1,3-dicarboxylato] monohydrate]
title_short catena-Poly[[[aqua(1,10-phenanthroline)manganese(II)]-μ-adamantane-1,3-dicarboxylato] monohydrate]
title_full catena-Poly[[[aqua(1,10-phenanthroline)manganese(II)]-μ-adamantane-1,3-dicarboxylato] monohydrate]
title_fullStr catena-Poly[[[aqua(1,10-phenanthroline)manganese(II)]-μ-adamantane-1,3-dicarboxylato] monohydrate]
title_full_unstemmed catena-Poly[[[aqua(1,10-phenanthroline)manganese(II)]-μ-adamantane-1,3-dicarboxylato] monohydrate]
title_sort catena-poly[[[aqua(1,10-phenanthroline)manganese(ii)]-μ-adamantane-1,3-dicarboxylato] monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-11-01
description In the title coordination polymer, {[Mn(C12H14O4)(C12H8N2)(H2O)]·H2O}n, the MnII atom has a highly distorted cis-MnN2O4 octahedral geometry arising from its coordination by a bidentate phenanthroline ligand, a water molecule and monodentate and bidentate adamantane-1,3-dicarboxylate dianions. The bridging dianion leads to [001] chains in the crystal. The chains are linked by O—H...O hydrogen bonds, involving both the coordinated and uncoordinated water molecules, thereby forming a two-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811041900
work_keys_str_mv AT jianqiangliu catenapolyaqua110phenanthrolinemanganeseiiamp956adamantane13dicarboxylatomonohydrate
AT yunshenghuang catenapolyaqua110phenanthrolinemanganeseiiamp956adamantane13dicarboxylatomonohydrate
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