Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]

Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]

In the title compound, {[CdCl2(C16H20N4)2]·4H2O}n, octahedrally coordinated CdII ions, situated on crystallographic inversion centres, bearing trans-disposed chloride ligands, are linked into (4,4)-grid coordination polymer layers by tethering 1,4-bis(3-pyridylmethyl)piperazine ligands....

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Bibliographic Details
Main Authors: Karyn M. Blake, Robert L. LaDuca
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809027767
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spelling doaj-dc0f0cac08d5495e871200fd61fe6c022020-11-24T21:26:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m947m94710.1107/S1600536809027767Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]Karyn M. BlakeRobert L. LaDucaIn the title compound, {[CdCl2(C16H20N4)2]·4H2O}n, octahedrally coordinated CdII ions, situated on crystallographic inversion centres, bearing trans-disposed chloride ligands, are linked into (4,4)-grid coordination polymer layers by tethering 1,4-bis(3-pyridylmethyl)piperazine ligands. The layers are aligned parallel to the (overline{1}01) crystal planes and aggregate by means of O—H...N, O—H...O and O—H...Cl hydrogen-bonding mechanisms imparted by cyclic water molecule tetramers. http://scripts.iucr.org/cgi-bin/paper?S1600536809027767
collection DOAJ
language English
format Article
sources DOAJ
author Karyn M. Blake
Robert L. LaDuca
spellingShingle Karyn M. Blake
Robert L. LaDuca
Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]
Acta Crystallographica Section E
author_facet Karyn M. Blake
Robert L. LaDuca
author_sort Karyn M. Blake
title Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]
title_short Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]
title_full Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]
title_fullStr Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]
title_full_unstemmed Poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2N:N′]dichloridocadmium(II)] tetrahydrate]
title_sort poly[[bis[μ-1,4-bis(3-pyridylmethyl)piperazine-κ2n:n′]dichloridocadmium(ii)] tetrahydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-08-01
description In the title compound, {[CdCl2(C16H20N4)2]·4H2O}n, octahedrally coordinated CdII ions, situated on crystallographic inversion centres, bearing trans-disposed chloride ligands, are linked into (4,4)-grid coordination polymer layers by tethering 1,4-bis(3-pyridylmethyl)piperazine ligands. The layers are aligned parallel to the (overline{1}01) crystal planes and aggregate by means of O—H...N, O—H...O and O—H...Cl hydrogen-bonding mechanisms imparted by cyclic water molecule tetramers.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809027767
work_keys_str_mv AT karynmblake polybisamp95614bis3pyridylmethylpiperazineamp9542nnamp8242dichloridocadmiumiitetrahydrate
AT robertlladuca polybisamp95614bis3pyridylmethylpiperazineamp9542nnamp8242dichloridocadmiumiitetrahydrate
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