Bis(cyclohexylammonium) tetrachloridodiphenylstannate(IV)

Bis(cyclohexylammonium) tetrachloridodiphenylstannate(IV)

The title compound, (C6H14N)2[Sn(C6H5)2Cl4], contains cyclohexylammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The SnIV atom in the complex anion is surrounded by four Cl− ligands and two trans-phenyl groups in a distorted octahedral config...

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Main Authors: Modou Sarr, Carina Merkens, Aminata Diassé-Sarr, Libasse Diop, Ulli Englert
Format: Article
Language:English
Published: International Union of Crystallography 2014-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681401109X
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spelling doaj-dacc3141661847479a60c5dbaa8178662020-11-25T01:58:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-06-01706m220m22110.1107/S160053681401109Xwm5023Bis(cyclohexylammonium) tetrachloridodiphenylstannate(IV)Modou Sarr0Carina Merkens1Aminata Diassé-Sarr2Libasse Diop3Ulli Englert4Laboratoire de Chimie Minerale et Analytique, Département de Chimie, Faculté des Sciences et Techniques Université Cheikh Anta Diop, Dakar, SenegalInstitut für Anorganische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, GermanyLaboratoire de Chimie Minerale et Analytique, Département de Chimie, Faculté des Sciences et Techniques Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minerale et Analytique, Département de Chimie, Faculté des Sciences et Techniques Université Cheikh Anta Diop, Dakar, SenegalInstitut für Anorganische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, GermanyThe title compound, (C6H14N)2[Sn(C6H5)2Cl4], contains cyclohexylammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The SnIV atom in the complex anion is surrounded by four Cl− ligands and two trans-phenyl groups in a distorted octahedral configuration. The anions are connected with the cations through N—H...Cl hydrogen bonds. Every cation is involved in three N—H...Cl bonds to the chloride ligands of three different anions, and each chloride ligand is linked to two cations. This arrangement leads to a layered structure parallel to (010).http://scripts.iucr.org/cgi-bin/paper?S160053681401109X
collection DOAJ
language English
format Article
sources DOAJ
author Modou Sarr
Carina Merkens
Aminata Diassé-Sarr
Libasse Diop
Ulli Englert
spellingShingle Modou Sarr
Carina Merkens
Aminata Diassé-Sarr
Libasse Diop
Ulli Englert
Bis(cyclohexylammonium) tetrachloridodiphenylstannate(IV)
Acta Crystallographica Section E
author_facet Modou Sarr
Carina Merkens
Aminata Diassé-Sarr
Libasse Diop
Ulli Englert
author_sort Modou Sarr
title Bis(cyclohexylammonium) tetrachloridodiphenylstannate(IV)
title_short Bis(cyclohexylammonium) tetrachloridodiphenylstannate(IV)
title_full Bis(cyclohexylammonium) tetrachloridodiphenylstannate(IV)
title_fullStr Bis(cyclohexylammonium) tetrachloridodiphenylstannate(IV)
title_full_unstemmed Bis(cyclohexylammonium) tetrachloridodiphenylstannate(IV)
title_sort bis(cyclohexylammonium) tetrachloridodiphenylstannate(iv)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-06-01
description The title compound, (C6H14N)2[Sn(C6H5)2Cl4], contains cyclohexylammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The SnIV atom in the complex anion is surrounded by four Cl− ligands and two trans-phenyl groups in a distorted octahedral configuration. The anions are connected with the cations through N—H...Cl hydrogen bonds. Every cation is involved in three N—H...Cl bonds to the chloride ligands of three different anions, and each chloride ligand is linked to two cations. This arrangement leads to a layered structure parallel to (010).
url http://scripts.iucr.org/cgi-bin/paper?S160053681401109X
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AT carinamerkens biscyclohexylammoniumtetrachloridodiphenylstannateiv
AT aminatadiassesarr biscyclohexylammoniumtetrachloridodiphenylstannateiv
AT libassediop biscyclohexylammoniumtetrachloridodiphenylstannateiv
AT ullienglert biscyclohexylammoniumtetrachloridodiphenylstannateiv
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