(1S,2R,3S,6S,7R)-3,7,11,11-Tetramethyl-6,7-epoxybicyclo[5.4.0]undecane-2-ol

(1S,2R,3S,6S,7R)-3,7,11,11-Tetramethyl-6,7-epoxybicyclo[5.4.0]undecane-2-ol

The title compound, C15H26O2, was synthesized from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the Atlas cedar (cedrus atlantica). The molecule is built up from a seven-membered ring to which a six- and a three-membered ring are fused. The...

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Main Authors: Mohamed Loubidi, Ahmed Benharref, Lahcen El Ammari, Mohamed Saadi, Moha Berraho
Format: Article
Language:English
Published: International Union of Crystallography 2014-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814008642
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spelling doaj-daac761d430a42e58ef342c661df71ba2020-11-25T01:40:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-05-01705o595o59510.1107/S1600536814008642bt6976(1S,2R,3S,6S,7R)-3,7,11,11-Tetramethyl-6,7-epoxybicyclo[5.4.0]undecane-2-olMohamed Loubidi0Ahmed Benharref1Lahcen El Ammari2Mohamed Saadi3Moha Berraho4Laboratoire de Chimie des Substances Naturelles, "Unité Associé au CNRST (URAC16)", Faculté des Sciences Semlalia, BP 2390 Bd My Abdellah, 40000 Marrakech, MoroccoLaboratoire de Chimie des Substances Naturelles, "Unité Associé au CNRST (URAC16)", Faculté des Sciences Semlalia, BP 2390 Bd My Abdellah, 40000 Marrakech, MoroccoLaboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, BP 1014, Avenue Ibn Battouta, Rabat, MoroccoLaboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, BP 1014, Avenue Ibn Battouta, Rabat, MoroccoLaboratoire de Chimie des Substances Naturelles, "Unité Associé au CNRST (URAC16)", Faculté des Sciences Semlalia, BP 2390 Bd My Abdellah, 40000 Marrakech, MoroccoThe title compound, C15H26O2, was synthesized from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the Atlas cedar (cedrus atlantica). The molecule is built up from a seven-membered ring to which a six- and a three-membered ring are fused. The seven- and six-membered rings each have a twist-boat conformation. In the crystal, O—H...O hydrogen bonds link the molecules into zigzag chains running along the b-axis direction.http://scripts.iucr.org/cgi-bin/paper?S1600536814008642
collection DOAJ
language English
format Article
sources DOAJ
author Mohamed Loubidi
Ahmed Benharref
Lahcen El Ammari
Mohamed Saadi
Moha Berraho
spellingShingle Mohamed Loubidi
Ahmed Benharref
Lahcen El Ammari
Mohamed Saadi
Moha Berraho
(1S,2R,3S,6S,7R)-3,7,11,11-Tetramethyl-6,7-epoxybicyclo[5.4.0]undecane-2-ol
Acta Crystallographica Section E
author_facet Mohamed Loubidi
Ahmed Benharref
Lahcen El Ammari
Mohamed Saadi
Moha Berraho
author_sort Mohamed Loubidi
title (1S,2R,3S,6S,7R)-3,7,11,11-Tetramethyl-6,7-epoxybicyclo[5.4.0]undecane-2-ol
title_short (1S,2R,3S,6S,7R)-3,7,11,11-Tetramethyl-6,7-epoxybicyclo[5.4.0]undecane-2-ol
title_full (1S,2R,3S,6S,7R)-3,7,11,11-Tetramethyl-6,7-epoxybicyclo[5.4.0]undecane-2-ol
title_fullStr (1S,2R,3S,6S,7R)-3,7,11,11-Tetramethyl-6,7-epoxybicyclo[5.4.0]undecane-2-ol
title_full_unstemmed (1S,2R,3S,6S,7R)-3,7,11,11-Tetramethyl-6,7-epoxybicyclo[5.4.0]undecane-2-ol
title_sort (1s,2r,3s,6s,7r)-3,7,11,11-tetramethyl-6,7-epoxybicyclo[5.4.0]undecane-2-ol
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-05-01
description The title compound, C15H26O2, was synthesized from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the Atlas cedar (cedrus atlantica). The molecule is built up from a seven-membered ring to which a six- and a three-membered ring are fused. The seven- and six-membered rings each have a twist-boat conformation. In the crystal, O—H...O hydrogen bonds link the molecules into zigzag chains running along the b-axis direction.
url http://scripts.iucr.org/cgi-bin/paper?S1600536814008642
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AT lahcenelammari 1s2r3s6s7r371111tetramethyl67epoxybicyclo540undecane2ol
AT mohamedsaadi 1s2r3s6s7r371111tetramethyl67epoxybicyclo540undecane2ol
AT mohaberraho 1s2r3s6s7r371111tetramethyl67epoxybicyclo540undecane2ol
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