Kinetics and mechanism of the oxidation of some substituted aldonitrones by quinolinium chlorochromate in aqueous DMF medium in the absence and presence of oxalic acid

Kinetics and mechanism of the oxidation of some substituted aldonitrones by quinolinium chlorochromate in aqueous DMF medium in the absence and presence of oxalic acid

The kinetics of the oxidation of aldonitrones (nitrone) by quinolinium chlorochromate (QCC) was determined in 50 % DMF-water in the absence and presence of oxalic acid in order to study the effect of oxalic acid. It was considered worthwhile to investigate whether it undergoes co-oxidation or just f...

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Bibliographic Details
Main Authors: Rajarajan Govindasamy, Jayachandramani Natesan, Manivarman Subramanian, Jayabharathi Jayaraman, Thanikachalam Venugopal
Format: Article
Language:English
Published: Serbian Chemical Society 2009-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
aldonitrones
quinolinium chlorochromate
isokinetic plot
entropy
enthalpy
free energy
oxalic acid
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2009/0352-51390902171R.pdf

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http://www.doiserbia.nb.rs/img/doi/0352-5139/2009/0352-51390902171R.pdf

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