Bis(2-fluorobenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)lead(II) dihydrate

Bis(2-fluorobenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)lead(II) dihydrate

In the title compound, [Pb(C7H4FO2)2(C12H8N2)2]·2H2O, the PbII atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluorobenzoate ligands in an irregular polyhedral coordination geometry. Two carboxylate O atoms...

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Main Author: Bi-Song Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2009-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809035016
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spelling doaj-da641f4555f645f299ec5a3ec9eb898c2020-11-24T21:25:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510m1167m116810.1107/S1600536809035016Bis(2-fluorobenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)lead(II) dihydrateBi-Song ZhangIn the title compound, [Pb(C7H4FO2)2(C12H8N2)2]·2H2O, the PbII atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluorobenzoate ligands in an irregular polyhedral coordination geometry. Two carboxylate O atoms and one F atom are each disordered over two sites with occupancy factors of 0.60 and 0.40. The dihedral angle between the two phen ligands is 89.9 (1)°. The mean interplanar distances are alternatively of 3.44 (3) and 3.45 (3) Å, indicating π–π stacking interactions between the neighboring phen ligands. In the crystal, O—H...O, O—H...F and C—H...O hydrogen bonds link the complex molecules and uncoordinated water molecules into a supramolecular network. http://scripts.iucr.org/cgi-bin/paper?S1600536809035016
collection DOAJ
language English
format Article
sources DOAJ
author Bi-Song Zhang
spellingShingle Bi-Song Zhang
Bis(2-fluorobenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)lead(II) dihydrate
Acta Crystallographica Section E
author_facet Bi-Song Zhang
author_sort Bi-Song Zhang
title Bis(2-fluorobenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)lead(II) dihydrate
title_short Bis(2-fluorobenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)lead(II) dihydrate
title_full Bis(2-fluorobenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)lead(II) dihydrate
title_fullStr Bis(2-fluorobenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)lead(II) dihydrate
title_full_unstemmed Bis(2-fluorobenzoato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)lead(II) dihydrate
title_sort bis(2-fluorobenzoato-κ2o,o′)bis(1,10-phenanthroline-κ2n,n′)lead(ii) dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-10-01
description In the title compound, [Pb(C7H4FO2)2(C12H8N2)2]·2H2O, the PbII atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluorobenzoate ligands in an irregular polyhedral coordination geometry. Two carboxylate O atoms and one F atom are each disordered over two sites with occupancy factors of 0.60 and 0.40. The dihedral angle between the two phen ligands is 89.9 (1)°. The mean interplanar distances are alternatively of 3.44 (3) and 3.45 (3) Å, indicating π–π stacking interactions between the neighboring phen ligands. In the crystal, O—H...O, O—H...F and C—H...O hydrogen bonds link the complex molecules and uncoordinated water molecules into a supramolecular network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809035016
work_keys_str_mv AT bisongzhang bis2fluorobenzoatoamp9542ooamp8242bis110phenanthrolineamp9542nnamp8242leadiidihydrate
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