Diammonium aqua(ethylenediaminetetraacetato)iron(II) trihydrate

Diammonium aqua(ethylenediaminetetraacetato)iron(II) trihydrate

In the title compound, (NH4)2[Fe(C10H12N2O8)(H2O)]·3H2O, the FeII center is in a distorted pentagonal-bipyramidal geometry. Two carboxylate O and two N atoms from the ethylenediaminetetraacetate (EDTA) ion and one O atom from coordinated water comprise the equatorial plane. Two other carbox...

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Main Authors: Hua-Ming Huang, Hong-Bing Yang, Xiang-Yu Li, Fang-Fang Ren
Format: Article
Language:English
Published: International Union of Crystallography 2009-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808042190
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spelling doaj-da4caebacdb54a78b61990559276591f2020-11-25T00:46:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m87m8810.1107/S1600536808042190Diammonium aqua(ethylenediaminetetraacetato)iron(II) trihydrateHua-Ming HuangHong-Bing YangXiang-Yu LiFang-Fang RenIn the title compound, (NH4)2[Fe(C10H12N2O8)(H2O)]·3H2O, the FeII center is in a distorted pentagonal-bipyramidal geometry. Two carboxylate O and two N atoms from the ethylenediaminetetraacetate (EDTA) ion and one O atom from coordinated water comprise the equatorial plane. Two other carboxylate O atoms from the EDTA ion occupy the apical sites. Both ammonium cations and all water molecules function as hydrogen-bond donors, and ten N—H...O and nine O—H...O hydrogen bonds form a three-dimensional network between the complex anions, cations and the water molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536808042190
collection DOAJ
language English
format Article
sources DOAJ
author Hua-Ming Huang
Hong-Bing Yang
Xiang-Yu Li
Fang-Fang Ren
spellingShingle Hua-Ming Huang
Hong-Bing Yang
Xiang-Yu Li
Fang-Fang Ren
Diammonium aqua(ethylenediaminetetraacetato)iron(II) trihydrate
Acta Crystallographica Section E
author_facet Hua-Ming Huang
Hong-Bing Yang
Xiang-Yu Li
Fang-Fang Ren
author_sort Hua-Ming Huang
title Diammonium aqua(ethylenediaminetetraacetato)iron(II) trihydrate
title_short Diammonium aqua(ethylenediaminetetraacetato)iron(II) trihydrate
title_full Diammonium aqua(ethylenediaminetetraacetato)iron(II) trihydrate
title_fullStr Diammonium aqua(ethylenediaminetetraacetato)iron(II) trihydrate
title_full_unstemmed Diammonium aqua(ethylenediaminetetraacetato)iron(II) trihydrate
title_sort diammonium aqua(ethylenediaminetetraacetato)iron(ii) trihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-01-01
description In the title compound, (NH4)2[Fe(C10H12N2O8)(H2O)]·3H2O, the FeII center is in a distorted pentagonal-bipyramidal geometry. Two carboxylate O and two N atoms from the ethylenediaminetetraacetate (EDTA) ion and one O atom from coordinated water comprise the equatorial plane. Two other carboxylate O atoms from the EDTA ion occupy the apical sites. Both ammonium cations and all water molecules function as hydrogen-bond donors, and ten N—H...O and nine O—H...O hydrogen bonds form a three-dimensional network between the complex anions, cations and the water molecules.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808042190
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AT hongbingyang diammoniumaquaethylenediaminetetraacetatoironiitrihydrate
AT xiangyuli diammoniumaquaethylenediaminetetraacetatoironiitrihydrate
AT fangfangren diammoniumaquaethylenediaminetetraacetatoironiitrihydrate
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