Analogies between Vanadoborates and Planar Aromatic Hydrocarbons: A High-Spin Analogue of Aromaticity
The vanadium-vanadium interactions in the polygonal aggregates of d1 vanadium(IV) atoms, with a total of 4k + 2 vanadium electrons (k an integer) imbedded in an electronically inactive borate matrix in certain vanadoborate structures are analogous to the ring carbon-carbon interactions in diamagneti...
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| Format: | Article |
| Language: | English |
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MDPI AG
2017-12-01
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| Series: | Materials |
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| Online Access: | https://www.mdpi.com/1996-1944/11/1/15 |