Bromidotricarbonyl[4-iodo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]rhenium(I)

Bromidotricarbonyl[4-iodo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]rhenium(I)

In the title compound, [ReBr(C12H9IN2)(CO)3], the coordination geometry of the ReI ion is a distorted fac-ReC3BrN2 octahedron, arising from the N,N′-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the...

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Main Authors: Ali Mahmoudi, Saeed Dehghanpour
Format: Article
Language:English
Published: International Union of Crystallography 2010-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810037104
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spelling doaj-d999795e30d348ce8e5d8eaeeadf4d402020-11-25T02:31:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1335m133510.1107/S1600536810037104Bromidotricarbonyl[4-iodo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]rhenium(I)Ali MahmoudiSaeed DehghanpourIn the title compound, [ReBr(C12H9IN2)(CO)3], the coordination geometry of the ReI ion is a distorted fac-ReC3BrN2 octahedron, arising from the N,N′-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the 4-iodo-N-(pyridin-2-ylmethylidene)aniline ligand is 46.2 (3)°. The bromide ion and its corresponding trans CO molecule are disordered over two sets of sites in a 0.966 (3):0.034 (3) ratio. http://scripts.iucr.org/cgi-bin/paper?S1600536810037104
collection DOAJ
language English
format Article
sources DOAJ
author Ali Mahmoudi
Saeed Dehghanpour
spellingShingle Ali Mahmoudi
Saeed Dehghanpour
Bromidotricarbonyl[4-iodo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]rhenium(I)
Acta Crystallographica Section E
author_facet Ali Mahmoudi
Saeed Dehghanpour
author_sort Ali Mahmoudi
title Bromidotricarbonyl[4-iodo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]rhenium(I)
title_short Bromidotricarbonyl[4-iodo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]rhenium(I)
title_full Bromidotricarbonyl[4-iodo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]rhenium(I)
title_fullStr Bromidotricarbonyl[4-iodo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]rhenium(I)
title_full_unstemmed Bromidotricarbonyl[4-iodo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]rhenium(I)
title_sort bromidotricarbonyl[4-iodo-n-(pyridin-2-ylmethylidene)aniline-κ2n,n′]rhenium(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-10-01
description In the title compound, [ReBr(C12H9IN2)(CO)3], the coordination geometry of the ReI ion is a distorted fac-ReC3BrN2 octahedron, arising from the N,N′-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the 4-iodo-N-(pyridin-2-ylmethylidene)aniline ligand is 46.2 (3)°. The bromide ion and its corresponding trans CO molecule are disordered over two sets of sites in a 0.966 (3):0.034 (3) ratio.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810037104
work_keys_str_mv AT alimahmoudi bromidotricarbonyl4iodonpyridin2ylmethylideneanilineamp9542nnamp8242rheniumi
AT saeeddehghanpour bromidotricarbonyl4iodonpyridin2ylmethylideneanilineamp9542nnamp8242rheniumi
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