trans-Chloridotetrakis(4-methylpyridine-κN)(nitrosyl-κN)ruthenium(II) bis(hexafluoridophosphate) acetone 0.75-solvate

trans-Chloridotetrakis(4-methylpyridine-κN)(nitrosyl-κN)ruthenium(II) bis(hexafluoridophosphate) acetone 0.75-solvate

The title compound, [RuCl(NO)(C6H7N)4](PF6)2·0.75(CH3)2CO, comprises four ligands of 4-picoline in equatorial position around the central atom. Overall, the complex features an octahedral coordination environment around the central RuII atom, with the chlorido ligand trans to the nitrosyl. The bond...

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Bibliographic Details
Main Authors: Hasan Shamran Mohammed, Sonia Mallet-Ladeira, Benoit Cormary, Marine Tassé, Isabelle Malfant
Format: Article
Language:English
Published: International Union of Crystallography 2017-12-01
Series:IUCrData
Subjects:
crystal structure
ruthenium nitrosyl
picoline
compressed octahedral coordination environment
nitric oxide
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314617017618
Description
Summary:The title compound, [RuCl(NO)(C6H7N)4](PF6)2·0.75(CH3)2CO, comprises four ligands of 4-picoline in equatorial position around the central atom. Overall, the complex features an octahedral coordination environment around the central RuII atom, with the chlorido ligand trans to the nitrosyl. The bond length of the nitrosyl N=O ligand is 1.140 (5) Å, while the angle Ru—N=O is 179.0 (4)°. The asymmetric unit contains four PF6− counter-anions, two with occupancy of 0.25 and one with occupancy of 0.5. One PF6− anion is disordered over two sets of sites and one other is disordered with an acetone molecule that occupies the same site.
ISSN:2414-3146

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