Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions

High-valent metal nitrides are difficult to stabilise due to the high thermodynamic stability and chemical inertness of N2. Here, the authors employ a large volume press to prepare an iron(IV) nitridoferrate Ca4FeIVN4 from Fe2N and Ca3N2 via azide-mediated oxidation under high pressure conditions.

Bibliographic Details
Main Authors:	Simon D. Kloß, Arthur Haffner, Pascal Manuel, Masato Goto, Yuichi Shimakawa, J. Paul Attfield
Format:	Article
Language:	English
Published:	Nature Publishing Group 2021-01-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-020-20881-y

id	doaj-d9671dfd9f124e13884e329a3f5ad3b2
record_format	Article
spelling	doaj-d9671dfd9f124e13884e329a3f5ad3b22021-01-31T12:18:57ZengNature Publishing GroupNature Communications2041-17232021-01-011211610.1038/s41467-020-20881-yPreparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditionsSimon D. Kloß0Arthur Haffner1Pascal Manuel2Masato Goto3Yuichi Shimakawa4J. Paul Attfield5University of Edinburgh, Centre for Science at Extreme Conditions and School of ChemistryLudwig-Maximilians-University Munich, Department ChemistryISIS Neutron Source, STFC Rutherford Appleton Laboratory, OxfordshireInstitute for Chemical Research, Kyoto University, UjiInstitute for Chemical Research, Kyoto University, UjiUniversity of Edinburgh, Centre for Science at Extreme Conditions and School of ChemistryHigh-valent metal nitrides are difficult to stabilise due to the high thermodynamic stability and chemical inertness of N2. Here, the authors employ a large volume press to prepare an iron(IV) nitridoferrate Ca4FeIVN4 from Fe2N and Ca3N2 via azide-mediated oxidation under high pressure conditions.https://doi.org/10.1038/s41467-020-20881-y
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Simon D. Kloß Arthur Haffner Pascal Manuel Masato Goto Yuichi Shimakawa J. Paul Attfield
spellingShingle	Simon D. Kloß Arthur Haffner Pascal Manuel Masato Goto Yuichi Shimakawa J. Paul Attfield Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions Nature Communications
author_facet	Simon D. Kloß Arthur Haffner Pascal Manuel Masato Goto Yuichi Shimakawa J. Paul Attfield
author_sort	Simon D. Kloß
title	Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
title_short	Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
title_full	Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
title_fullStr	Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
title_full_unstemmed	Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
title_sort	preparation of iron(iv) nitridoferrate ca4fen4 through azide-mediated oxidation under high-pressure conditions
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2021-01-01
description	High-valent metal nitrides are difficult to stabilise due to the high thermodynamic stability and chemical inertness of N2. Here, the authors employ a large volume press to prepare an iron(IV) nitridoferrate Ca4FeIVN4 from Fe2N and Ca3N2 via azide-mediated oxidation under high pressure conditions.
url	https://doi.org/10.1038/s41467-020-20881-y
work_keys_str_mv	AT simondkloß preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions AT arthurhaffner preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions AT pascalmanuel preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions AT masatogoto preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions AT yuichishimakawa preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions AT jpaulattfield preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions
_version_	1724317339911979008

Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions

Similar Items