Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]

Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]

The asymmetric unit of the title compound, [K(C5HF6N2)(H2O)2]n, is composed of two 3,5-bis(trifluoromethyl)pyrazolide anions, two potassium cations and four water molecules. The water molecules and 3,5-bis(trifluoromethyl)pyrazolide anions act as bridges between the potassium cations. Each potassium...

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Main Authors: Hien Ngoc Phan, Hans-Wolfram Lerner, Michael Bolte
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810027133
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spelling doaj-d91e0c92f1e0427e9cf3ffab6f4a317c2020-11-25T02:11:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m928m92810.1107/S1600536810027133Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]Hien Ngoc PhanHans-Wolfram LernerMichael BolteThe asymmetric unit of the title compound, [K(C5HF6N2)(H2O)2]n, is composed of two 3,5-bis(trifluoromethyl)pyrazolide anions, two potassium cations and four water molecules. The water molecules and 3,5-bis(trifluoromethyl)pyrazolide anions act as bridges between the potassium cations. Each potassium cation is surrounded by four O atoms [K—O = 2.705 (3)–2.767 (3) Å] and four F atoms [K—F = 2.870 (7)–3.215 (13) Å]. The water molecules and the 3,5-bis(trifluoromethyl)pyrazolide anions are connected by O—H...N hydrogen bonds, forming layers in the ab plane. All –CF3 groups show rotational disorder between two orientations each. http://scripts.iucr.org/cgi-bin/paper?S1600536810027133
collection DOAJ
language English
format Article
sources DOAJ
author Hien Ngoc Phan
Hans-Wolfram Lerner
Michael Bolte
spellingShingle Hien Ngoc Phan
Hans-Wolfram Lerner
Michael Bolte
Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]
Acta Crystallographica Section E
author_facet Hien Ngoc Phan
Hans-Wolfram Lerner
Michael Bolte
author_sort Hien Ngoc Phan
title Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]
title_short Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]
title_full Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]
title_fullStr Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]
title_full_unstemmed Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]
title_sort poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-08-01
description The asymmetric unit of the title compound, [K(C5HF6N2)(H2O)2]n, is composed of two 3,5-bis(trifluoromethyl)pyrazolide anions, two potassium cations and four water molecules. The water molecules and 3,5-bis(trifluoromethyl)pyrazolide anions act as bridges between the potassium cations. Each potassium cation is surrounded by four O atoms [K—O = 2.705 (3)–2.767 (3) Å] and four F atoms [K—F = 2.870 (7)–3.215 (13) Å]. The water molecules and the 3,5-bis(trifluoromethyl)pyrazolide anions are connected by O—H...N hydrogen bonds, forming layers in the ab plane. All –CF3 groups show rotational disorder between two orientations each.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810027133
work_keys_str_mv AT hienngocphan polydiaqua35bistrifluoromethylpyrazolidopotassium
AT hanswolframlerner polydiaqua35bistrifluoromethylpyrazolidopotassium
AT michaelbolte polydiaqua35bistrifluoromethylpyrazolidopotassium
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