trans-Carbonylchloridobis(tri-o-tolylphosphane-κP)rhodium(I)

trans-Carbonylchloridobis(tri-o-tolylphosphane-κP)rhodium(I)

In the title compound, [RhCl(C21H21P)2(CO)], the coordination geometry around the RhI atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the RhI atom lies on a center of in...

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Main Authors: Stefan Warsink, Renier Koen, Andreas Roodt
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811045715
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spelling doaj-d91a87f4964d4a44a0b90ec0df9f25bf2020-11-25T01:11:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1666m166610.1107/S1600536811045715trans-Carbonylchloridobis(tri-o-tolylphosphane-κP)rhodium(I)Stefan WarsinkRenier KoenAndreas RoodtIn the title compound, [RhCl(C21H21P)2(CO)], the coordination geometry around the RhI atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the RhI atom lies on a center of inversion. The effective cone angle ΘE for the title compound is 169.0 (3)°. There are no significant intermolecular interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536811045715
collection DOAJ
language English
format Article
sources DOAJ
author Stefan Warsink
Renier Koen
Andreas Roodt
spellingShingle Stefan Warsink
Renier Koen
Andreas Roodt
trans-Carbonylchloridobis(tri-o-tolylphosphane-κP)rhodium(I)
Acta Crystallographica Section E
author_facet Stefan Warsink
Renier Koen
Andreas Roodt
author_sort Stefan Warsink
title trans-Carbonylchloridobis(tri-o-tolylphosphane-κP)rhodium(I)
title_short trans-Carbonylchloridobis(tri-o-tolylphosphane-κP)rhodium(I)
title_full trans-Carbonylchloridobis(tri-o-tolylphosphane-κP)rhodium(I)
title_fullStr trans-Carbonylchloridobis(tri-o-tolylphosphane-κP)rhodium(I)
title_full_unstemmed trans-Carbonylchloridobis(tri-o-tolylphosphane-κP)rhodium(I)
title_sort trans-carbonylchloridobis(tri-o-tolylphosphane-κp)rhodium(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-12-01
description In the title compound, [RhCl(C21H21P)2(CO)], the coordination geometry around the RhI atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the RhI atom lies on a center of inversion. The effective cone angle ΘE for the title compound is 169.0 (3)°. There are no significant intermolecular interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811045715
work_keys_str_mv AT stefanwarsink transcarbonylchloridobistriotolylphosphaneamp954prhodiumi
AT renierkoen transcarbonylchloridobistriotolylphosphaneamp954prhodiumi
AT andreasroodt transcarbonylchloridobistriotolylphosphaneamp954prhodiumi
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