trans-Carbonylchloridobis(tri-o-tolylphosphane-κP)rhodium(I)
In the title compound, [RhCl(C21H21P)2(CO)], the coordination geometry around the RhI atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the RhI atom lies on a center of in...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-12-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811045715 |
| Summary: | In the title compound, [RhCl(C21H21P)2(CO)], the coordination geometry around the RhI atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the RhI atom lies on a center of inversion. The effective cone angle ΘE for the title compound is 169.0 (3)°. There are no significant intermolecular interactions. |
|---|---|
| ISSN: | 1600-5368 |