Bis(ethylenediamine-κ2N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvate

Bis(ethylenediamine-κ2N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvate

In the cation of the title compound, [Cu(C2H8N2)2(CH3OH)2](C8H4O4)·2CH3OH, the CuII atom lies on an inversion centre. The four N atoms of two ethylenediamine ligands around the CuII atom form the equatorial plane, while two methanol O atoms in the axial positions complete a Jahn&amp...

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Main Authors: Abolfazl Abbaszadeh, Nasser Safari, Vahid Amani, Behrouz Notash
Format: Article
Language:English
Published: International Union of Crystallography 2012-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812028942
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spelling doaj-d8ee1a07d9894010bd430fb261b071c82020-11-25T01:04:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m1012m101210.1107/S1600536812028942Bis(ethylenediamine-κ2N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvateAbolfazl AbbaszadehNasser SafariVahid AmaniBehrouz NotashIn the cation of the title compound, [Cu(C2H8N2)2(CH3OH)2](C8H4O4)·2CH3OH, the CuII atom lies on an inversion centre. The four N atoms of two ethylenediamine ligands around the CuII atom form the equatorial plane, while two methanol O atoms in the axial positions complete a Jahn–Teller distorted octahedral coordination. The benzene-1,4-dicarboxylate anion is centrosymmetric. In the crystal, C—H...O, N—H...O and O—H...O hydrogen bonds link the cations, the anions and the methanol solvent molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536812028942
collection DOAJ
language English
format Article
sources DOAJ
author Abolfazl Abbaszadeh
Nasser Safari
Vahid Amani
Behrouz Notash
spellingShingle Abolfazl Abbaszadeh
Nasser Safari
Vahid Amani
Behrouz Notash
Bis(ethylenediamine-κ2N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvate
Acta Crystallographica Section E
author_facet Abolfazl Abbaszadeh
Nasser Safari
Vahid Amani
Behrouz Notash
author_sort Abolfazl Abbaszadeh
title Bis(ethylenediamine-κ2N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvate
title_short Bis(ethylenediamine-κ2N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvate
title_full Bis(ethylenediamine-κ2N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvate
title_fullStr Bis(ethylenediamine-κ2N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvate
title_full_unstemmed Bis(ethylenediamine-κ2N,N′)bis(methanol-κO)copper(II) benzene-1,4-dicarboxylate methanol disolvate
title_sort bis(ethylenediamine-κ2n,n′)bis(methanol-κo)copper(ii) benzene-1,4-dicarboxylate methanol disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-07-01
description In the cation of the title compound, [Cu(C2H8N2)2(CH3OH)2](C8H4O4)·2CH3OH, the CuII atom lies on an inversion centre. The four N atoms of two ethylenediamine ligands around the CuII atom form the equatorial plane, while two methanol O atoms in the axial positions complete a Jahn–Teller distorted octahedral coordination. The benzene-1,4-dicarboxylate anion is centrosymmetric. In the crystal, C—H...O, N—H...O and O—H...O hydrogen bonds link the cations, the anions and the methanol solvent molecules.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812028942
work_keys_str_mv AT abolfazlabbaszadeh bisethylenediamineamp9542nnamp8242bismethanolamp954ocopperiibenzene14dicarboxylatemethanoldisolvate
AT nassersafari bisethylenediamineamp9542nnamp8242bismethanolamp954ocopperiibenzene14dicarboxylatemethanoldisolvate
AT vahidamani bisethylenediamineamp9542nnamp8242bismethanolamp954ocopperiibenzene14dicarboxylatemethanoldisolvate
AT behrouznotash bisethylenediamineamp9542nnamp8242bismethanolamp954ocopperiibenzene14dicarboxylatemethanoldisolvate
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