(2R)-8-Benzyl-2-[(S)-hydroxy(phenyl)methyl]-8-azabicyclo[3.2.1]octan-3-one

(2R)-8-Benzyl-2-[(S)-hydroxy(phenyl)methyl]-8-azabicyclo[3.2.1]octan-3-one

The crystal of the title compound, C21H23NO2, was chosen from a conglomerate formed by a racemic mixture. An intramolecular hydrogen bond is formed between hydroxy group and heterocyclic N atom of the azabicyclo[3.2.1]octan-3-one system. The crystal structure is stabilized by C—H...O i...

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Main Authors: Krzysztof Brzezinski, Ryszard Lazny, Michal Sienkiewicz, Sławomir Wojtulewski, Zbigniew Dauter
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811053190
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spelling doaj-d8d0c505a8824d54abbc86ae6e3af50a2020-11-25T03:26:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681o149o15010.1107/S1600536811053190(2R)-8-Benzyl-2-[(S)-hydroxy(phenyl)methyl]-8-azabicyclo[3.2.1]octan-3-oneKrzysztof BrzezinskiRyszard LaznyMichal SienkiewiczSławomir WojtulewskiZbigniew DauterThe crystal of the title compound, C21H23NO2, was chosen from a conglomerate formed by a racemic mixture. An intramolecular hydrogen bond is formed between hydroxy group and heterocyclic N atom of the azabicyclo[3.2.1]octan-3-one system. The crystal structure is stabilized by C—H...O interactions between aliphatic C—H groups and the carbonyl O atom. For the title chiral crystal, the highly redundant and accurate diffraction data set collected with low energy copper radiation gave a Flack parameter of 0.12 (18) for anomalous scattering effects originating from O atoms.http://scripts.iucr.org/cgi-bin/paper?S1600536811053190
collection DOAJ
language English
format Article
sources DOAJ
author Krzysztof Brzezinski
Ryszard Lazny
Michal Sienkiewicz
Sławomir Wojtulewski
Zbigniew Dauter
spellingShingle Krzysztof Brzezinski
Ryszard Lazny
Michal Sienkiewicz
Sławomir Wojtulewski
Zbigniew Dauter
(2R)-8-Benzyl-2-[(S)-hydroxy(phenyl)methyl]-8-azabicyclo[3.2.1]octan-3-one
Acta Crystallographica Section E
author_facet Krzysztof Brzezinski
Ryszard Lazny
Michal Sienkiewicz
Sławomir Wojtulewski
Zbigniew Dauter
author_sort Krzysztof Brzezinski
title (2R)-8-Benzyl-2-[(S)-hydroxy(phenyl)methyl]-8-azabicyclo[3.2.1]octan-3-one
title_short (2R)-8-Benzyl-2-[(S)-hydroxy(phenyl)methyl]-8-azabicyclo[3.2.1]octan-3-one
title_full (2R)-8-Benzyl-2-[(S)-hydroxy(phenyl)methyl]-8-azabicyclo[3.2.1]octan-3-one
title_fullStr (2R)-8-Benzyl-2-[(S)-hydroxy(phenyl)methyl]-8-azabicyclo[3.2.1]octan-3-one
title_full_unstemmed (2R)-8-Benzyl-2-[(S)-hydroxy(phenyl)methyl]-8-azabicyclo[3.2.1]octan-3-one
title_sort (2r)-8-benzyl-2-[(s)-hydroxy(phenyl)methyl]-8-azabicyclo[3.2.1]octan-3-one
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-01-01
description The crystal of the title compound, C21H23NO2, was chosen from a conglomerate formed by a racemic mixture. An intramolecular hydrogen bond is formed between hydroxy group and heterocyclic N atom of the azabicyclo[3.2.1]octan-3-one system. The crystal structure is stabilized by C—H...O interactions between aliphatic C—H groups and the carbonyl O atom. For the title chiral crystal, the highly redundant and accurate diffraction data set collected with low energy copper radiation gave a Flack parameter of 0.12 (18) for anomalous scattering effects originating from O atoms.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811053190
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AT ryszardlazny 2r8benzyl2shydroxyphenylmethyl8azabicyclo321octan3one
AT michalsienkiewicz 2r8benzyl2shydroxyphenylmethyl8azabicyclo321octan3one
AT samp322awomirwojtulewski 2r8benzyl2shydroxyphenylmethyl8azabicyclo321octan3one
AT zbigniewdauter 2r8benzyl2shydroxyphenylmethyl8azabicyclo321octan3one
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