Poly[di-μ2-chlorido-tri-μ2-terephthalato-tetralead(II)]

The title compound, [Pb4(C8H4O4)3Cl2]n, consists of a three-dimensional inorganic–organic hybrid framework. The asymmetric unit contains two Pb2+ cations, one Cl− anion and one and a half terephthalate anions, the latter being completed by inversion symmetry. The two Pb2+...

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Main Authors: Lei Yang, Zhongyue Li, Guanghua Li
Format: Article
Language:English
Published: International Union of Crystallography 2011-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681101779X
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spelling doaj-d8b168f2c76f4757be89d238034cb21b2020-11-25T02:43:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m761m76110.1107/S160053681101779XPoly[di-μ2-chlorido-tri-μ2-terephthalato-tetralead(II)]Lei YangZhongyue LiGuanghua LiThe title compound, [Pb4(C8H4O4)3Cl2]n, consists of a three-dimensional inorganic–organic hybrid framework. The asymmetric unit contains two Pb2+ cations, one Cl− anion and one and a half terephthalate anions, the latter being completed by inversion symmetry. The two Pb2+ cations are each surrounded by five O atoms and one Cl atom in the form of irregular polyhedra. The cations are linked by μ2-O and μ2-Cl atoms into binuclear units, which are further extended through Pb—O interactions into an undulated inorganic layer parallel to (001). These layers are connected along [001] by the terephthalate groups into a three-dimensional framework. http://scripts.iucr.org/cgi-bin/paper?S160053681101779X
collection DOAJ
language English
format Article
sources DOAJ
author Lei Yang
Zhongyue Li
Guanghua Li
spellingShingle Lei Yang
Zhongyue Li
Guanghua Li
Poly[di-μ2-chlorido-tri-μ2-terephthalato-tetralead(II)]
Acta Crystallographica Section E
author_facet Lei Yang
Zhongyue Li
Guanghua Li
author_sort Lei Yang
title Poly[di-μ2-chlorido-tri-μ2-terephthalato-tetralead(II)]
title_short Poly[di-μ2-chlorido-tri-μ2-terephthalato-tetralead(II)]
title_full Poly[di-μ2-chlorido-tri-μ2-terephthalato-tetralead(II)]
title_fullStr Poly[di-μ2-chlorido-tri-μ2-terephthalato-tetralead(II)]
title_full_unstemmed Poly[di-μ2-chlorido-tri-μ2-terephthalato-tetralead(II)]
title_sort poly[di-μ2-chlorido-tri-μ2-terephthalato-tetralead(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-06-01
description The title compound, [Pb4(C8H4O4)3Cl2]n, consists of a three-dimensional inorganic–organic hybrid framework. The asymmetric unit contains two Pb2+ cations, one Cl− anion and one and a half terephthalate anions, the latter being completed by inversion symmetry. The two Pb2+ cations are each surrounded by five O atoms and one Cl atom in the form of irregular polyhedra. The cations are linked by μ2-O and μ2-Cl atoms into binuclear units, which are further extended through Pb—O interactions into an undulated inorganic layer parallel to (001). These layers are connected along [001] by the terephthalate groups into a three-dimensional framework.
url http://scripts.iucr.org/cgi-bin/paper?S160053681101779X
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AT guanghuali polydiamp9562chloridotriamp9562terephthalatotetraleadii
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