Crystal structure of silver [(propane-1,3-diyldinitrilo-κ2N,N′)tetraacetato-κ4O,O′,O′′,O′′′]chromate(III) from synchrotron X-ray data

The asymmetric unit of the title compound, Ag[Cr(C11H14N2O8)]·3H2O, contains one [Cr(1,3-pdta)]− anion [1,3-pdta is (propane-1,3-diyldinitrilo)tetraacetate], one Ag+ cation and three water molecules. The Cr3+ ion is coordinated to the four O and two N atoms of the 1,3-pdta ligand, displaying a disto...

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Main Authors:	Dohyun Moon, Keon Sang Ryoo, Jong-Ha Choi
Format:	Article
Language:	English
Published:	International Union of Crystallography 2018-03-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure propane-1,3-diyldinitrilotetraacetate silver cation chromate(III) complex twist-boat conformer
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989018001743

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spelling	doaj-d8ac865d6eb14cf08a4f943d6c31438d2020-11-24T21:26:58ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-03-0174327828110.1107/S2056989018001743nk2244Crystal structure of silver [(propane-1,3-diyldinitrilo-κ2N,N′)tetraacetato-κ4O,O′,O′′,O′′′]chromate(III) from synchrotron X-ray dataDohyun Moon0Keon Sang Ryoo1Jong-Ha Choi2Pohang Accelerator Laboratory, POSTECH, Pohang 37673, Republic of KoreaDepartment of Chemistry, Andong National University, Andong 36729, Republic of KoreaDepartment of Chemistry, Andong National University, Andong 36729, Republic of KoreaThe asymmetric unit of the title compound, Ag[Cr(C11H14N2O8)]·3H2O, contains one [Cr(1,3-pdta)]− anion [1,3-pdta is (propane-1,3-diyldinitrilo)tetraacetate], one Ag+ cation and three water molecules. The Cr3+ ion is coordinated to the four O and two N atoms of the 1,3-pdta ligand, displaying a distorted octahedral geometry. The mean Cr—N and Cr—O bond lengths are 2.0727 (17) and 1.9608 (15) Å, respectively. The conformations of the chelate rings were found to be envelope for the glycinates and twist-boat for the six-membered diamine (T) ring. The Ag+ cation is surrounded by six O atoms from three non-coordinated carbonyl O atoms of neighbouring 1,3-pdta groups and three water molecules. The crystal structure is stabilized by intermolecular hydrogen bonding involving the water O—H group as donor and the carboxyl O atom as acceptor.http://scripts.iucr.org/cgi-bin/paper?S2056989018001743crystal structurepropane-1,3-diyldinitrilotetraacetatesilver cationchromate(III) complextwist-boat conformer
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Dohyun Moon Keon Sang Ryoo Jong-Ha Choi
spellingShingle	Dohyun Moon Keon Sang Ryoo Jong-Ha Choi Crystal structure of silver [(propane-1,3-diyldinitrilo-κ2N,N′)tetraacetato-κ4O,O′,O′′,O′′′]chromate(III) from synchrotron X-ray data Acta Crystallographica Section E: Crystallographic Communications crystal structure propane-1,3-diyldinitrilotetraacetate silver cation chromate(III) complex twist-boat conformer
author_facet	Dohyun Moon Keon Sang Ryoo Jong-Ha Choi
author_sort	Dohyun Moon
title	Crystal structure of silver [(propane-1,3-diyldinitrilo-κ2N,N′)tetraacetato-κ4O,O′,O′′,O′′′]chromate(III) from synchrotron X-ray data
title_short	Crystal structure of silver [(propane-1,3-diyldinitrilo-κ2N,N′)tetraacetato-κ4O,O′,O′′,O′′′]chromate(III) from synchrotron X-ray data
title_full	Crystal structure of silver [(propane-1,3-diyldinitrilo-κ2N,N′)tetraacetato-κ4O,O′,O′′,O′′′]chromate(III) from synchrotron X-ray data
title_fullStr	Crystal structure of silver [(propane-1,3-diyldinitrilo-κ2N,N′)tetraacetato-κ4O,O′,O′′,O′′′]chromate(III) from synchrotron X-ray data
title_full_unstemmed	Crystal structure of silver [(propane-1,3-diyldinitrilo-κ2N,N′)tetraacetato-κ4O,O′,O′′,O′′′]chromate(III) from synchrotron X-ray data
title_sort	crystal structure of silver [(propane-1,3-diyldinitrilo-κ2n,n′)tetraacetato-κ4o,o′,o′′,o′′′]chromate(iii) from synchrotron x-ray data
publisher	International Union of Crystallography
series	Acta Crystallographica Section E: Crystallographic Communications
issn	2056-9890
publishDate	2018-03-01
description	The asymmetric unit of the title compound, Ag[Cr(C11H14N2O8)]·3H2O, contains one [Cr(1,3-pdta)]− anion [1,3-pdta is (propane-1,3-diyldinitrilo)tetraacetate], one Ag+ cation and three water molecules. The Cr3+ ion is coordinated to the four O and two N atoms of the 1,3-pdta ligand, displaying a distorted octahedral geometry. The mean Cr—N and Cr—O bond lengths are 2.0727 (17) and 1.9608 (15) Å, respectively. The conformations of the chelate rings were found to be envelope for the glycinates and twist-boat for the six-membered diamine (T) ring. The Ag+ cation is surrounded by six O atoms from three non-coordinated carbonyl O atoms of neighbouring 1,3-pdta groups and three water molecules. The crystal structure is stabilized by intermolecular hydrogen bonding involving the water O—H group as donor and the carboxyl O atom as acceptor.
topic	crystal structure propane-1,3-diyldinitrilotetraacetate silver cation chromate(III) complex twist-boat conformer
url	http://scripts.iucr.org/cgi-bin/paper?S2056989018001743
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Crystal structure of silver [(propane-1,3-diyldinitrilo-κ2N,N′)tetraacetato-κ4O,O′,O′′,O′′′]chromate(III) from synchrotron X-ray data

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