Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition

Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition

Understanding the interplay between electronic structure and performance and how it relates to mechanism is important for catalysis. Here the authors report an asymmetric [3+2] cycloaddition and show the Ni(II) catalyst possesses a weakly bound acetate ligand, leaving thedz2orbital partially vacant.

Bibliographic Details
Main Authors: Yoshihiro Sohtome, Genta Nakamura, Atsuya Muranaka, Daisuke Hashizume, Sylvain Lectard, Teruhisa Tsuchimoto, Masanobu Uchiyama, Mikiko Sodeoka
Format: Article
Language:English
Published: Nature Publishing Group 2017-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/ncomms14875
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spelling doaj-d8a3542ba4944c2a933d8921207793e42021-05-11T07:05:58ZengNature Publishing GroupNature Communications2041-17232017-04-018111010.1038/ncomms14875Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloadditionYoshihiro Sohtome0Genta Nakamura1Atsuya Muranaka2Daisuke Hashizume3Sylvain Lectard4Teruhisa Tsuchimoto5Masanobu Uchiyama6Mikiko Sodeoka7Synthetic Organic Chemistry Laboratory, RIKENSynthetic Organic Chemistry Laboratory, RIKENRIKEN Center for Sustainable Resource ScienceRIKEN Center for Emergent Matter ScienceSynthetic Organic Chemistry Laboratory, RIKENDepartment of Applied Chemistry, School of Science and Technology, Meiji UniversityRIKEN Center for Sustainable Resource ScienceSynthetic Organic Chemistry Laboratory, RIKENUnderstanding the interplay between electronic structure and performance and how it relates to mechanism is important for catalysis. Here the authors report an asymmetric [3+2] cycloaddition and show the Ni(II) catalyst possesses a weakly bound acetate ligand, leaving thedz2orbital partially vacant.https://doi.org/10.1038/ncomms14875
collection DOAJ
language English
format Article
sources DOAJ
author Yoshihiro Sohtome
Genta Nakamura
Atsuya Muranaka
Daisuke Hashizume
Sylvain Lectard
Teruhisa Tsuchimoto
Masanobu Uchiyama
Mikiko Sodeoka
spellingShingle Yoshihiro Sohtome
Genta Nakamura
Atsuya Muranaka
Daisuke Hashizume
Sylvain Lectard
Teruhisa Tsuchimoto
Masanobu Uchiyama
Mikiko Sodeoka
Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
Nature Communications
author_facet Yoshihiro Sohtome
Genta Nakamura
Atsuya Muranaka
Daisuke Hashizume
Sylvain Lectard
Teruhisa Tsuchimoto
Masanobu Uchiyama
Mikiko Sodeoka
author_sort Yoshihiro Sohtome
title Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
title_short Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
title_full Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
title_fullStr Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
title_full_unstemmed Naked d-orbital in a centrochiral Ni(II) complex as a catalyst for asymmetric [3+2] cycloaddition
title_sort naked d-orbital in a centrochiral ni(ii) complex as a catalyst for asymmetric [3+2] cycloaddition
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2017-04-01
description Understanding the interplay between electronic structure and performance and how it relates to mechanism is important for catalysis. Here the authors report an asymmetric [3+2] cycloaddition and show the Ni(II) catalyst possesses a weakly bound acetate ligand, leaving thedz2orbital partially vacant.
url https://doi.org/10.1038/ncomms14875
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AT gentanakamura nakeddorbitalinacentrochiralniiicomplexasacatalystforasymmetric32cycloaddition
AT atsuyamuranaka nakeddorbitalinacentrochiralniiicomplexasacatalystforasymmetric32cycloaddition
AT daisukehashizume nakeddorbitalinacentrochiralniiicomplexasacatalystforasymmetric32cycloaddition
AT sylvainlectard nakeddorbitalinacentrochiralniiicomplexasacatalystforasymmetric32cycloaddition
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AT masanobuuchiyama nakeddorbitalinacentrochiralniiicomplexasacatalystforasymmetric32cycloaddition
AT mikikosodeoka nakeddorbitalinacentrochiralniiicomplexasacatalystforasymmetric32cycloaddition
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