Poly[diaquabis(&#956;3-1H-benzimidazole-5,6-dicarboxylato-&#954;4N3:O5,O5&#8242;:O6)bis(&#956;2-1H,3H-benzimidazolium-5,6-dicarboxylato-&#954;3O5,O5&#8242;:O6)digadolinium(III)]

In the title complex, [Gd2(C9H4N2O4)2(C9H5N2O4)2(H2O)2]n, two of the benzimidazole-5,6-dicarboxylate ligands are protonated at the imidazole groups. Each GdIII ion is coordinated by six O atoms and one N atom from five ligands and one water molecule, displaying a distorted bicapped trigonal-prismati...

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Main Authors:	Rong-Hua Zeng, Qing-Yang Lian, Chun-De Huang, Yi-Yi Wu, Jie-Xuan Huang
Format:	Article
Language:	English
Published:	International Union of Crystallography 2009-12-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536809046819

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spelling	doaj-d84a2bca93034070b7f7d83f809e2b0b2020-11-25T01:11:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1566m156710.1107/S1600536809046819Poly[diaquabis(&#956;3-1H-benzimidazole-5,6-dicarboxylato-&#954;4N3:O5,O5&#8242;:O6)bis(&#956;2-1H,3H-benzimidazolium-5,6-dicarboxylato-&#954;3O5,O5&#8242;:O6)digadolinium(III)]Rong-Hua ZengQing-Yang LianChun-De HuangYi-Yi WuJie-Xuan HuangIn the title complex, [Gd2(C9H4N2O4)2(C9H5N2O4)2(H2O)2]n, two of the benzimidazole-5,6-dicarboxylate ligands are protonated at the imidazole groups. Each GdIII ion is coordinated by six O atoms and one N atom from five ligands and one water molecule, displaying a distorted bicapped trigonal-prismatic geometry. The GdIII ions are linked by the carboxylate groups and imidazole N atoms, forming a layer parallel to (001). These layers are further connected by O&#8212;H...O and N&#8212;H...O hydrogen bonds into a three-dimensional supramolecular network. http://scripts.iucr.org/cgi-bin/paper?S1600536809046819
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Rong-Hua Zeng Qing-Yang Lian Chun-De Huang Yi-Yi Wu Jie-Xuan Huang
spellingShingle	Rong-Hua Zeng Qing-Yang Lian Chun-De Huang Yi-Yi Wu Jie-Xuan Huang Poly[diaquabis(&#956;3-1H-benzimidazole-5,6-dicarboxylato-&#954;4N3:O5,O5&#8242;:O6)bis(&#956;2-1H,3H-benzimidazolium-5,6-dicarboxylato-&#954;3O5,O5&#8242;:O6)digadolinium(III)] Acta Crystallographica Section E
author_facet	Rong-Hua Zeng Qing-Yang Lian Chun-De Huang Yi-Yi Wu Jie-Xuan Huang
author_sort	Rong-Hua Zeng
title	Poly[diaquabis(&#956;3-1H-benzimidazole-5,6-dicarboxylato-&#954;4N3:O5,O5&#8242;:O6)bis(&#956;2-1H,3H-benzimidazolium-5,6-dicarboxylato-&#954;3O5,O5&#8242;:O6)digadolinium(III)]
title_short	Poly[diaquabis(&#956;3-1H-benzimidazole-5,6-dicarboxylato-&#954;4N3:O5,O5&#8242;:O6)bis(&#956;2-1H,3H-benzimidazolium-5,6-dicarboxylato-&#954;3O5,O5&#8242;:O6)digadolinium(III)]
title_full	Poly[diaquabis(&#956;3-1H-benzimidazole-5,6-dicarboxylato-&#954;4N3:O5,O5&#8242;:O6)bis(&#956;2-1H,3H-benzimidazolium-5,6-dicarboxylato-&#954;3O5,O5&#8242;:O6)digadolinium(III)]
title_fullStr	Poly[diaquabis(&#956;3-1H-benzimidazole-5,6-dicarboxylato-&#954;4N3:O5,O5&#8242;:O6)bis(&#956;2-1H,3H-benzimidazolium-5,6-dicarboxylato-&#954;3O5,O5&#8242;:O6)digadolinium(III)]
title_full_unstemmed	Poly[diaquabis(&#956;3-1H-benzimidazole-5,6-dicarboxylato-&#954;4N3:O5,O5&#8242;:O6)bis(&#956;2-1H,3H-benzimidazolium-5,6-dicarboxylato-&#954;3O5,O5&#8242;:O6)digadolinium(III)]
title_sort	poly[diaquabis(&#956;3-1h-benzimidazole-5,6-dicarboxylato-&#954;4n3:o5,o5&#8242;:o6)bis(&#956;2-1h,3h-benzimidazolium-5,6-dicarboxylato-&#954;3o5,o5&#8242;:o6)digadolinium(iii)]
publisher	International Union of Crystallography
series	Acta Crystallographica Section E
issn	1600-5368
publishDate	2009-12-01
description	In the title complex, [Gd2(C9H4N2O4)2(C9H5N2O4)2(H2O)2]n, two of the benzimidazole-5,6-dicarboxylate ligands are protonated at the imidazole groups. Each GdIII ion is coordinated by six O atoms and one N atom from five ligands and one water molecule, displaying a distorted bicapped trigonal-prismatic geometry. The GdIII ions are linked by the carboxylate groups and imidazole N atoms, forming a layer parallel to (001). These layers are further connected by O&#8212;H...O and N&#8212;H...O hydrogen bonds into a three-dimensional supramolecular network.
url	http://scripts.iucr.org/cgi-bin/paper?S1600536809046819
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Poly[diaquabis(&amp;#956;3-1H-benzimidazole-5,6-dicarboxylato-&amp;#954;4N3:O5,O5&amp;#8242;:O6)bis(&amp;#956;2-1H,3H-benzimidazolium-5,6-dicarboxylato-&amp;#954;3O5,O5&amp;#8242;:O6)digadolinium(III)]

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