cis-Dichloridobis[2-(hydroxymethyl)tetrahydrofuran-κ2O,O′]manganese(II)

cis-Dichloridobis[2-(hydroxymethyl)tetrahydrofuran-κ2O,O′]manganese(II)

The structure of the title compound, [MnCl2(C5H10O2)2], was solved from low-temperature data collected at 100 (2) K. The asymmetric unit contains one half-molecule with the MnII ion located on a twofold axis. A distorted octahedral environment around the Mn atom is formed by two...

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Main Authors: Piotr Sobota, Józef Utko, Lucjan B. Jerzykiewcz
Format: Article
Language:English
Published: International Union of Crystallography 2008-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808009549
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spelling doaj-d7ba061637d9480b8a34af2ce6d71ab12020-11-24T21:31:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645m657m65810.1107/S1600536808009549cis-Dichloridobis[2-(hydroxymethyl)tetrahydrofuran-κ2O,O′]manganese(II)Piotr SobotaJózef UtkoLucjan B. JerzykiewczThe structure of the title compound, [MnCl2(C5H10O2)2], was solved from low-temperature data collected at 100 (2) K. The asymmetric unit contains one half-molecule with the MnII ion located on a twofold axis. A distorted octahedral environment around the Mn atom is formed by two ether and two hydroxyl O atoms of two 2-(hydroxymethyl)tetrahydrofuran ligands, and by two chloride ions. The chelating tetrahydrofuran ligands, which form five-membered rings, are cis oriented. The crystal structure is stabilized by hydrogen bonding between the coordinated OH groups and the chloride ions.http://scripts.iucr.org/cgi-bin/paper?S1600536808009549
collection DOAJ
language English
format Article
sources DOAJ
author Piotr Sobota
Józef Utko
Lucjan B. Jerzykiewcz
spellingShingle Piotr Sobota
Józef Utko
Lucjan B. Jerzykiewcz
cis-Dichloridobis[2-(hydroxymethyl)tetrahydrofuran-κ2O,O′]manganese(II)
Acta Crystallographica Section E
author_facet Piotr Sobota
Józef Utko
Lucjan B. Jerzykiewcz
author_sort Piotr Sobota
title cis-Dichloridobis[2-(hydroxymethyl)tetrahydrofuran-κ2O,O′]manganese(II)
title_short cis-Dichloridobis[2-(hydroxymethyl)tetrahydrofuran-κ2O,O′]manganese(II)
title_full cis-Dichloridobis[2-(hydroxymethyl)tetrahydrofuran-κ2O,O′]manganese(II)
title_fullStr cis-Dichloridobis[2-(hydroxymethyl)tetrahydrofuran-κ2O,O′]manganese(II)
title_full_unstemmed cis-Dichloridobis[2-(hydroxymethyl)tetrahydrofuran-κ2O,O′]manganese(II)
title_sort cis-dichloridobis[2-(hydroxymethyl)tetrahydrofuran-κ2o,o′]manganese(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-05-01
description The structure of the title compound, [MnCl2(C5H10O2)2], was solved from low-temperature data collected at 100 (2) K. The asymmetric unit contains one half-molecule with the MnII ion located on a twofold axis. A distorted octahedral environment around the Mn atom is formed by two ether and two hydroxyl O atoms of two 2-(hydroxymethyl)tetrahydrofuran ligands, and by two chloride ions. The chelating tetrahydrofuran ligands, which form five-membered rings, are cis oriented. The crystal structure is stabilized by hydrogen bonding between the coordinated OH groups and the chloride ions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808009549
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AT j243zefutko cisdichloridobis2hydroxymethyltetrahydrofuran9542oo8242manganeseii
AT lucjanbjerzykiewcz cisdichloridobis2hydroxymethyltetrahydrofuran9542oo8242manganeseii
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