(E)-2-[1-(3-Amino-4-chlorophenylimino)ethyl]-4-bromophenol

(E)-2-[1-(3-Amino-4-chlorophenylimino)ethyl]-4-bromophenol

The title Schiff base compound, C14H12BrClN2O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intramolecular O—...

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Main Authors: Hadariah Bahron, Siti Najihah Abu Bakar, Karimah Kassim, Chin Sing Yeap, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2010-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810009773
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spelling doaj-d792ead17a5e4d44bcd298f03772ed5e2020-11-25T01:13:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664o883o88310.1107/S1600536810009773(E)-2-[1-(3-Amino-4-chlorophenylimino)ethyl]-4-bromophenolHadariah BahronSiti Najihah Abu BakarKarimah KassimChin Sing YeapHoong-Kun FunThe title Schiff base compound, C14H12BrClN2O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intramolecular O—H...N hydrogen bond forms a six-membered ring, generating an S(6) ring motif. In the crystal structure, molecules are linked into chains along [010] via N—H...O hydrogen bonds. The presence of π–π interactions [centroid–centroid distance = 3.6244 (12) Å] further stabilizes the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810009773
collection DOAJ
language English
format Article
sources DOAJ
author Hadariah Bahron
Siti Najihah Abu Bakar
Karimah Kassim
Chin Sing Yeap
Hoong-Kun Fun
spellingShingle Hadariah Bahron
Siti Najihah Abu Bakar
Karimah Kassim
Chin Sing Yeap
Hoong-Kun Fun
(E)-2-[1-(3-Amino-4-chlorophenylimino)ethyl]-4-bromophenol
Acta Crystallographica Section E
author_facet Hadariah Bahron
Siti Najihah Abu Bakar
Karimah Kassim
Chin Sing Yeap
Hoong-Kun Fun
author_sort Hadariah Bahron
title (E)-2-[1-(3-Amino-4-chlorophenylimino)ethyl]-4-bromophenol
title_short (E)-2-[1-(3-Amino-4-chlorophenylimino)ethyl]-4-bromophenol
title_full (E)-2-[1-(3-Amino-4-chlorophenylimino)ethyl]-4-bromophenol
title_fullStr (E)-2-[1-(3-Amino-4-chlorophenylimino)ethyl]-4-bromophenol
title_full_unstemmed (E)-2-[1-(3-Amino-4-chlorophenylimino)ethyl]-4-bromophenol
title_sort (e)-2-[1-(3-amino-4-chlorophenylimino)ethyl]-4-bromophenol
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-04-01
description The title Schiff base compound, C14H12BrClN2O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intramolecular O—H...N hydrogen bond forms a six-membered ring, generating an S(6) ring motif. In the crystal structure, molecules are linked into chains along [010] via N—H...O hydrogen bonds. The presence of π–π interactions [centroid–centroid distance = 3.6244 (12) Å] further stabilizes the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810009773
work_keys_str_mv AT hadariahbahron e213amino4chlorophenyliminoethyl4bromophenol
AT sitinajihahabubakar e213amino4chlorophenyliminoethyl4bromophenol
AT karimahkassim e213amino4chlorophenyliminoethyl4bromophenol
AT chinsingyeap e213amino4chlorophenyliminoethyl4bromophenol
AT hoongkunfun e213amino4chlorophenyliminoethyl4bromophenol
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