Iron(II)-catalyzed trifluoromethylation of vinylcyclopropanes

An efficient iron(II)-catalyzed trifluoromethylation of vinylcyclopropanes was developed.A series of CF<sub>3</sub>-containing dihydronaphthalene derivatives were prepared with a moderate to high yield.This method offers several advantages in terms of its mild condition,readily available...

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Bibliographic Details
Main Authors: LI Zongrui, DENG Qinghai
Format: Article
Language:English
Published: Academic Journals Center of Shanghai Normal University 2016-12-01
Series:Journal of Shanghai Normal University (Natural Sciences)
Subjects:
Online Access:http://qktg.shnu.edu.cn/zrb/shsfqkszrb/ch/reader/create_pdf.aspx?file_no=201606004&flag=1&year_id=2016&quarter_id=6
Description
Summary:An efficient iron(II)-catalyzed trifluoromethylation of vinylcyclopropanes was developed.A series of CF<sub>3</sub>-containing dihydronaphthalene derivatives were prepared with a moderate to high yield.This method offers several advantages in terms of its mild condition,readily available and cheap catalyst,as well as short reaction time.Furthermore,the reaction mechanism was investigated preliminarily.
ISSN:1000-5137
1000-5137