[(Z)-N-Isopropyl-O-methylthiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I)
In the title compound, [Au(C5H10NOS)(C21H21P)], two independent molecules comprise the asymmetric unit, and these are connected by an aurophilic interaction [Au...Au = 3.1351 (3) Å]. Each AuI atom is linearly coordinated within a S,P-donor set with the distor...
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| Format: | Article |
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International Union of Crystallography
2009-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809046893 |
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doaj-d711b73235d848968ac95f263360eb882020-11-24T21:26:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1557m155710.1107/S1600536809046893[(Z)-N-Isopropyl-O-methylthiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I)Edward R. T. TiekinkPrimjira P. TadbuppaIn the title compound, [Au(C5H10NOS)(C21H21P)], two independent molecules comprise the asymmetric unit, and these are connected by an aurophilic interaction [Au...Au = 3.1351 (3) Å]. Each AuI atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry [S—Au—P = 175.31 (5) and 176.45 (5)°] ascribed to an intramolecular Au...O contact in each case [2.974 (4) and 3.027 (4) Å]. http://scripts.iucr.org/cgi-bin/paper?S1600536809046893 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Edward R. T. Tiekink Primjira P. Tadbuppa |
| spellingShingle |
Edward R. T. Tiekink Primjira P. Tadbuppa [(Z)-N-Isopropyl-O-methylthiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I) Acta Crystallographica Section E |
| author_facet |
Edward R. T. Tiekink Primjira P. Tadbuppa |
| author_sort |
Edward R. T. Tiekink |
| title |
[(Z)-N-Isopropyl-O-methylthiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I) |
| title_short |
[(Z)-N-Isopropyl-O-methylthiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I) |
| title_full |
[(Z)-N-Isopropyl-O-methylthiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I) |
| title_fullStr |
[(Z)-N-Isopropyl-O-methylthiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I) |
| title_full_unstemmed |
[(Z)-N-Isopropyl-O-methylthiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I) |
| title_sort |
[(z)-n-isopropyl-o-methylthiocarbamato-κs](tri-p-tolylphosphine-κp)gold(i) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-12-01 |
| description |
In the title compound, [Au(C5H10NOS)(C21H21P)], two independent molecules comprise the asymmetric unit, and these are connected by an aurophilic interaction [Au...Au = 3.1351 (3) Å]. Each AuI atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry [S—Au—P = 175.31 (5) and 176.45 (5)°] ascribed to an intramolecular Au...O contact in each case [2.974 (4) and 3.027 (4) Å]. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809046893 |
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AT edwardrttiekink znisopropylomethylthiocarbamatoamp954striptolylphosphineamp954pgoldi AT primjiraptadbuppa znisopropylomethylthiocarbamatoamp954striptolylphosphineamp954pgoldi |
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1725978383812132864 |