(Z)-5-Benzenecarbothioyl-1,11-dimethyl-6-phenyl-5H-dibenzo[d,f][1,3]diazepine
The seven-membered ring in the title compound, C28H22N2S, has a two-coordinate N atom as well as a three-coordinate N atom. The ring adopts a boat-shaped conformation with two C atoms of one methylphenyl ring as the stern and the three-coordinate N atom as the prow. The N,N-dimethylethanethioamide f...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811000092 |
| Summary: | The seven-membered ring in the title compound, C28H22N2S, has a two-coordinate N atom as well as a three-coordinate N atom. The ring adopts a boat-shaped conformation with two C atoms of one methylphenyl ring as the stern and the three-coordinate N atom as the prow. The N,N-dimethylethanethioamide fragment is nearly planar (r.m.s. deviation = 0.049 Å); the phenyl ring of the benzenecarbothioyl unit connected to the three-coordinate N atom is aligned at 83.72 (4)° with respect to the mean plane of this fragment. Weak intermolecular C—H...S hydrogen bonding is present in the crystal structure. |
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| ISSN: | 1600-5368 |