The Study of Electrochemical Behavior of Mono and Dinuclear Co(III) Complexes, trans-[pyCo((DO)(DOH)pn)(L)]PF6 and [{pyCo((DO)(DOH)pn)}2(μ-dicyd)](PF6)2

The Study of Electrochemical Behavior of Mono and Dinuclear Co(III) Complexes, trans-[pyCo((DO)(DOH)pn)(L)]PF6 and [{pyCo((DO)(DOH)pn)}2(μ-dicyd)](PF6)2

Electrochemical behavior of the new mono and dinuclear Co (III)  complexes of  the types trans-[pyCo((DO)(DOH)pn )(L)]PF6   and [{py Co((DO)(DOH)pn)}2 (μ-dicyd)] (PF6)2   have been studied in acetonitrile solution.  All the  mono nuclear complexes  show two quasi- reversible reduction couples associ...

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Bibliographic Details
Main Authors: Ali Reza Rezvani, Hassan Hadadzadeh
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2005-06-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
phenycyanamide
co(iii) complex
comproportionation equilibrium constant
oxime
Online Access:http://www.ijcce.ac.ir/article_8120_c7e58f90593bff0e8f7a7df17da9c9ff.pdf
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spelling doaj-d6656e9421a24838b4abed7035e3c1e32020-11-25T03:40:33ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99862005-06-0124217208120The Study of Electrochemical Behavior of Mono and Dinuclear Co(III) Complexes, trans-[pyCo((DO)(DOH)pn)(L)]PF6 and [{pyCo((DO)(DOH)pn)}2(μ-dicyd)](PF6)2Ali Reza Rezvani0Hassan Hadadzadeh1Chemistry Department, Sistan and Baluchestan University, P.O. Box 98135-674, Zahedan I. R. IRANChemistry Department, Sistan and Baluchestan University, P.O. Box 98135-674, Zahedan I. R. IRANElectrochemical behavior of the new mono and dinuclear Co (III)  complexes of  the types trans-[pyCo((DO)(DOH)pn )(L)]PF6   and [{py Co((DO)(DOH)pn)}2 (μ-dicyd)] (PF6)2   have been studied in acetonitrile solution.  All the  mono nuclear complexes  show two quasi- reversible reduction couples associate  to Co(III/II)and  Co(II/I). Each of these redox couples split to two  one electron  waves in dinuclear complex.http://www.ijcce.ac.ir/article_8120_c7e58f90593bff0e8f7a7df17da9c9ff.pdfphenycyanamideco(iii) complexcomproportionation equilibrium constantoxime
collection DOAJ
language English
format Article
sources DOAJ
author Ali Reza Rezvani
Hassan Hadadzadeh
spellingShingle Ali Reza Rezvani
Hassan Hadadzadeh
The Study of Electrochemical Behavior of Mono and Dinuclear Co(III) Complexes, trans-[pyCo((DO)(DOH)pn)(L)]PF6 and [{pyCo((DO)(DOH)pn)}2(μ-dicyd)](PF6)2
Iranian Journal of Chemistry & Chemical Engineering
phenycyanamide
co(iii) complex
comproportionation equilibrium constant
oxime
author_facet Ali Reza Rezvani
Hassan Hadadzadeh
author_sort Ali Reza Rezvani
title The Study of Electrochemical Behavior of Mono and Dinuclear Co(III) Complexes, trans-[pyCo((DO)(DOH)pn)(L)]PF6 and [{pyCo((DO)(DOH)pn)}2(μ-dicyd)](PF6)2
title_short The Study of Electrochemical Behavior of Mono and Dinuclear Co(III) Complexes, trans-[pyCo((DO)(DOH)pn)(L)]PF6 and [{pyCo((DO)(DOH)pn)}2(μ-dicyd)](PF6)2
title_full The Study of Electrochemical Behavior of Mono and Dinuclear Co(III) Complexes, trans-[pyCo((DO)(DOH)pn)(L)]PF6 and [{pyCo((DO)(DOH)pn)}2(μ-dicyd)](PF6)2
title_fullStr The Study of Electrochemical Behavior of Mono and Dinuclear Co(III) Complexes, trans-[pyCo((DO)(DOH)pn)(L)]PF6 and [{pyCo((DO)(DOH)pn)}2(μ-dicyd)](PF6)2
title_full_unstemmed The Study of Electrochemical Behavior of Mono and Dinuclear Co(III) Complexes, trans-[pyCo((DO)(DOH)pn)(L)]PF6 and [{pyCo((DO)(DOH)pn)}2(μ-dicyd)](PF6)2
title_sort study of electrochemical behavior of mono and dinuclear co(iii) complexes, trans-[pyco((do)(doh)pn)(l)]pf6 and [{pyco((do)(doh)pn)}2(μ-dicyd)](pf6)2
publisher Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
series Iranian Journal of Chemistry & Chemical Engineering
issn 1021-9986
1021-9986
publishDate 2005-06-01
description Electrochemical behavior of the new mono and dinuclear Co (III)  complexes of  the types trans-[pyCo((DO)(DOH)pn )(L)]PF6   and [{py Co((DO)(DOH)pn)}2 (μ-dicyd)] (PF6)2   have been studied in acetonitrile solution.  All the  mono nuclear complexes  show two quasi- reversible reduction couples associate  to Co(III/II)and  Co(II/I). Each of these redox couples split to two  one electron  waves in dinuclear complex.
topic phenycyanamide
co(iii) complex
comproportionation equilibrium constant
oxime
url http://www.ijcce.ac.ir/article_8120_c7e58f90593bff0e8f7a7df17da9c9ff.pdf
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