The Study of Electrochemical Behavior of Mono and Dinuclear Co(III) Complexes, trans-[pyCo((DO)(DOH)pn)(L)]PF6 and [{pyCo((DO)(DOH)pn)}2(μ-dicyd)](PF6)2

• Main Authors: Ali Reza Rezvani, Hassan Hadadzadeh
• Format: Article
• Language: English
• Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2005-06-01
• Series: Iranian Journal of Chemistry & Chemical Engineering
• Subjects: phenycyanamide; co(iii) complex; comproportionation equilibrium constant; oxime
• Online Access: http://www.ijcce.ac.ir/article_8120_c7e58f90593bff0e8f7a7df17da9c9ff.pdf
• ISSN: 1021-9986; 1021-9986

Electrochemical behavior of the new mono and dinuclear Co (III)  complexes of  the types trans-[pyCo((DO)(DOH)pn )(L)]PF6   and [{py Co((DO)(DOH)pn)}2 (μ-dicyd)] (PF6)2   have been studied in acetonitrile solution.  All the  mono nuclear complexes  show two quasi- reversible reduction couples associate  to Co(III/II)and  Co(II/I). Each of these redox couples split to two  one electron  waves in dinuclear complex.