Redox-triggered switching in three-dimensional covalent organic frameworks

Redox-triggered switching in three-dimensional covalent organic frameworks

Tuning of molecular switches in solid state toward stimuli-responsive materials attracted attention in recent years but has not yet been realized in three-dimensional (3D) covalent organic frameworks (COFs). Herein, the authors demonstrate a stable and switchable 3D COF which undergoes reversible tr...

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Main Authors: Chao Gao, Jian Li, Sheng Yin, Junliang Sun, Cheng Wang
Format: Article
Language:English
Published: Nature Publishing Group 2020-10-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-18588-1
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spelling doaj-d5e4cc57911a41b1a4ca3f0550b63bdd2021-10-03T11:51:23ZengNature Publishing GroupNature Communications2041-17232020-10-011111810.1038/s41467-020-18588-1Redox-triggered switching in three-dimensional covalent organic frameworksChao Gao0Jian Li1Sheng Yin2Junliang Sun3Cheng Wang4Sauvage Center for Molecular Sciences and Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan UniversityCollege of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Sciences, Peking UniversitySauvage Center for Molecular Sciences and Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan UniversityCollege of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Sciences, Peking UniversitySauvage Center for Molecular Sciences and Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan UniversityTuning of molecular switches in solid state toward stimuli-responsive materials attracted attention in recent years but has not yet been realized in three-dimensional (3D) covalent organic frameworks (COFs). Herein, the authors demonstrate a stable and switchable 3D COF which undergoes reversible transformation through a hydroquinone/quinone redox reaction.https://doi.org/10.1038/s41467-020-18588-1
collection DOAJ
language English
format Article
sources DOAJ
author Chao Gao
Jian Li
Sheng Yin
Junliang Sun
Cheng Wang
spellingShingle Chao Gao
Jian Li
Sheng Yin
Junliang Sun
Cheng Wang
Redox-triggered switching in three-dimensional covalent organic frameworks
Nature Communications
author_facet Chao Gao
Jian Li
Sheng Yin
Junliang Sun
Cheng Wang
author_sort Chao Gao
title Redox-triggered switching in three-dimensional covalent organic frameworks
title_short Redox-triggered switching in three-dimensional covalent organic frameworks
title_full Redox-triggered switching in three-dimensional covalent organic frameworks
title_fullStr Redox-triggered switching in three-dimensional covalent organic frameworks
title_full_unstemmed Redox-triggered switching in three-dimensional covalent organic frameworks
title_sort redox-triggered switching in three-dimensional covalent organic frameworks
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2020-10-01
description Tuning of molecular switches in solid state toward stimuli-responsive materials attracted attention in recent years but has not yet been realized in three-dimensional (3D) covalent organic frameworks (COFs). Herein, the authors demonstrate a stable and switchable 3D COF which undergoes reversible transformation through a hydroquinone/quinone redox reaction.
url https://doi.org/10.1038/s41467-020-18588-1
work_keys_str_mv AT chaogao redoxtriggeredswitchinginthreedimensionalcovalentorganicframeworks
AT jianli redoxtriggeredswitchinginthreedimensionalcovalentorganicframeworks
AT shengyin redoxtriggeredswitchinginthreedimensionalcovalentorganicframeworks
AT junliangsun redoxtriggeredswitchinginthreedimensionalcovalentorganicframeworks
AT chengwang redoxtriggeredswitchinginthreedimensionalcovalentorganicframeworks
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