catena-Poly[[nickel(II)-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4S,S′:N:N′-bis[(15-crown-5)magnesium(II)]-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4N:N′:S,S′] dichloride]

catena-Poly[[nickel(II)-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4S,S′:N:N′-bis[(15-crown-5)magnesium(II)]-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4N:N′:S,S′] dichloride]

The reaction of MgCl2, NiCl2, and Na2(i-mnt) (i-mnt is 1,1-dicyanothene-2,2-dithiolate) with 15-crown-5 (15-C-5) leads to an infinite chain polymer, {[NiMg2(C4N2S2)2(C10H20O5)2]Cl2}n or {[Mg(15-C-5)]2[Ni(i-mnt)2]Cl2}n, which consists of two [Mg(15-C-5)]2+ complex cations, one [Ni(i-mnt)2]2&#8722...

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Bibliographic Details
Main Authors: Junli Yang, Chengjuan Li, Dacheng Li, Daqi Wang
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807065622

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