1-(4-Iodobenzyl)-3-methylpyridinium bis(benzene-1,2-dithiolato)nickelate(III)
The asymmetric unit of the title compound, (C13H13IN)[Ni(C6H4S2)2], contains half each of two centrosymmetric anions and a single cation in a general position. In the anions, the NiIII ions are surrounded by four S atoms in a distorted square-planar geometry. In the crystal, the anions exhibit two d...
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International Union of Crystallography
2011-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811043522 |
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doaj-d5401189922a4df0bbee93cd094cf5da2020-11-24T21:26:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711m1607m160710.1107/S16005368110435221-(4-Iodobenzyl)-3-methylpyridinium bis(benzene-1,2-dithiolato)nickelate(III)Guang-Xiang LiuThe asymmetric unit of the title compound, (C13H13IN)[Ni(C6H4S2)2], contains half each of two centrosymmetric anions and a single cation in a general position. In the anions, the NiIII ions are surrounded by four S atoms in a distorted square-planar geometry. In the crystal, the anions exhibit two different packing modes by stacking along the a axis in face-to-face and side-by-side fashions. Interionic C—H...S hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.6947 (5) Å] are observed.http://scripts.iucr.org/cgi-bin/paper?S1600536811043522 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Guang-Xiang Liu |
| spellingShingle |
Guang-Xiang Liu 1-(4-Iodobenzyl)-3-methylpyridinium bis(benzene-1,2-dithiolato)nickelate(III) Acta Crystallographica Section E |
| author_facet |
Guang-Xiang Liu |
| author_sort |
Guang-Xiang Liu |
| title |
1-(4-Iodobenzyl)-3-methylpyridinium bis(benzene-1,2-dithiolato)nickelate(III) |
| title_short |
1-(4-Iodobenzyl)-3-methylpyridinium bis(benzene-1,2-dithiolato)nickelate(III) |
| title_full |
1-(4-Iodobenzyl)-3-methylpyridinium bis(benzene-1,2-dithiolato)nickelate(III) |
| title_fullStr |
1-(4-Iodobenzyl)-3-methylpyridinium bis(benzene-1,2-dithiolato)nickelate(III) |
| title_full_unstemmed |
1-(4-Iodobenzyl)-3-methylpyridinium bis(benzene-1,2-dithiolato)nickelate(III) |
| title_sort |
1-(4-iodobenzyl)-3-methylpyridinium bis(benzene-1,2-dithiolato)nickelate(iii) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-11-01 |
| description |
The asymmetric unit of the title compound, (C13H13IN)[Ni(C6H4S2)2], contains half each of two centrosymmetric anions and a single cation in a general position. In the anions, the NiIII ions are surrounded by four S atoms in a distorted square-planar geometry. In the crystal, the anions exhibit two different packing modes by stacking along the a axis in face-to-face and side-by-side fashions. Interionic C—H...S hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.6947 (5) Å] are observed. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811043522 |
| work_keys_str_mv |
AT guangxiangliu 14iodobenzyl3methylpyridiniumbisbenzene12dithiolatonickelateiii |
| _version_ |
1725978379562254336 |