Poly[(μ3-camphorato-κ3O:O′:O′′)(2-methyl-1H-imidazole-κN3)zinc(II)]

Poly[(μ3-camphorato-κ3O:O′:O′′)(2-methyl-1H-imidazole-κN3)zinc(II)]

In the title compound, [Zn(C10H14O4)(C4H6N2)]n, each ZnII ion is coordinated by one N atom from one 2-methyl-1H-imidazole ligand and three O atoms from two camphorate (cap) ligands in a distorted tetrahedral geometry. In one of the cap ligands, one methyl group is disordered between positions 1 and...

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Bibliographic Details
Main Authors: Haochen Shi, Chunjie Li, Feng Gao, Jingyan Chen, Fei Han
Format: Article
Language:English
Published: International Union of Crystallography 2010-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810007105
Description
Summary:In the title compound, [Zn(C10H14O4)(C4H6N2)]n, each ZnII ion is coordinated by one N atom from one 2-methyl-1H-imidazole ligand and three O atoms from two camphorate (cap) ligands in a distorted tetrahedral geometry. In one of the cap ligands, one methyl group is disordered between positions 1 and 3 in a 0.518 (12):0.482 (12) ratio. Each cap ligand bridges three ZnII ions, forming two-dimensional layers, which interact further via N—H...O hydrogen bonds.
ISSN:1600-5368

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