Catalytic Properties of the Dioxomolybdenum Siloxide MoO2(OSiPh3)2 and its 2,2'-Bipyridine Adduct MoO2(OSiPh3)2(bpy)
The tetrahedral triphenylsiloxy complex MoO2(OSiPh3)2 (1) and its Lewis baseadduct with 2,2'-bipyridine, MoO2(OSiPh3)2(bpy) (2), were prepared and characterised byIR/Raman spectroscopy, and thermogravimetric analysis. Both compounds catalyse theepoxidation of cis-cyclooctene at 55 oC using tert...
Main Authors: | Isabel S. Gonçalves, Paulo Ribeiro-Claro, Martyn Pillinger, Anabela A. Valente, Catarina Lourenço, Maria Salete Balula, Bernardo Monteiro, Sofia M. Bruno |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2006-04-01
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Series: | Molecules |
Subjects: | |
Online Access: | http://www.mdpi.com/1420-3049/11/4/298/ |
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