Catalytic Properties of the Dioxomolybdenum Siloxide MoO2(OSiPh3)2 and its 2,2'-Bipyridine Adduct MoO2(OSiPh3)2(bpy)

Catalytic Properties of the Dioxomolybdenum Siloxide MoO2(OSiPh3)2 and its 2,2'-Bipyridine Adduct MoO2(OSiPh3)2(bpy)

The tetrahedral triphenylsiloxy complex MoO2(OSiPh3)2 (1) and its Lewis baseadduct with 2,2'-bipyridine, MoO2(OSiPh3)2(bpy) (2), were prepared and characterised byIR/Raman spectroscopy, and thermogravimetric analysis. Both compounds catalyse theepoxidation of cis-cyclooctene at 55 oC using tert...

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Bibliographic Details
Main Authors: Isabel S. Gonçalves, Paulo Ribeiro-Claro, Martyn Pillinger, Anabela A. Valente, Catarina Lourenço, Maria Salete Balula, Bernardo Monteiro, Sofia M. Bruno
Format: Article
Language:English
Published: MDPI AG 2006-04-01
Series:Molecules
Subjects:
Dioxomolybdenum(VI) complexes
siloxide ligands
Lewis base adducts
2
2'-bipyridine
olefin epoxidation.
Online Access:http://www.mdpi.com/1420-3049/11/4/298/

Internet

http://www.mdpi.com/1420-3049/11/4/298/

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