Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)}

Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)}

In the dinuclear centrosymmetric CdII compound, [Cd2(C8H8NO2)4(C6H6N2O)2(H2O)2], the metal atom is chelated by two carboxylate groups from 4-(methylamino)benzoate (PMAB) anions, and coordinated by one nicotinamide and one water molecule; a carboxylate O atom from the adjacent PMAB anion bridges to t...

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Main Authors: Hacali Necefoğlu, Özgür Aybirdi, Barış Tercan, Tuncer Hökelek, Ertuğrul Gazi Sağlam
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810046258
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spelling doaj-d4c69c8442504d44baa3605e2738f5a52020-11-24T20:56:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1559m156010.1107/S1600536810046258Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)}Hacali NecefoğluÖzgür AybirdiBarış TercanTuncer HökelekErtuğrul Gazi SağlamIn the dinuclear centrosymmetric CdII compound, [Cd2(C8H8NO2)4(C6H6N2O)2(H2O)2], the metal atom is chelated by two carboxylate groups from 4-(methylamino)benzoate (PMAB) anions, and coordinated by one nicotinamide and one water molecule; a carboxylate O atom from the adjacent PMAB anion bridges to the Cd atom, completing the irregular seven-coordination geometry. In the crystal, intermolecular O—H...O, N—H...O and C—H...O hydrogen bonds link the molecules into a three-dimensional network. π–π contacts between the pyridine rings [centroid–centroid distance = 3.965 (1) Å] may further stabilize the structure. A weak C—H...π interaction also occurs. http://scripts.iucr.org/cgi-bin/paper?S1600536810046258
collection DOAJ
language English
format Article
sources DOAJ
author Hacali Necefoğlu
Özgür Aybirdi
Barış Tercan
Tuncer Hökelek
Ertuğrul Gazi Sağlam
spellingShingle Hacali Necefoğlu
Özgür Aybirdi
Barış Tercan
Tuncer Hökelek
Ertuğrul Gazi Sağlam
Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)}
Acta Crystallographica Section E
author_facet Hacali Necefoğlu
Özgür Aybirdi
Barış Tercan
Tuncer Hökelek
Ertuğrul Gazi Sağlam
author_sort Hacali Necefoğlu
title Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)}
title_short Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)}
title_full Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)}
title_fullStr Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)}
title_full_unstemmed Bis[μ-4-(methylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(methylamino)benzoato-κ2O,O′](nicotinamide-κN)cadmium(II)}
title_sort bis[μ-4-(methylamino)benzoato]-κ3o,o′:o;κ3o:o,o′-bis{aqua[4-(methylamino)benzoato-κ2o,o′](nicotinamide-κn)cadmium(ii)}
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description In the dinuclear centrosymmetric CdII compound, [Cd2(C8H8NO2)4(C6H6N2O)2(H2O)2], the metal atom is chelated by two carboxylate groups from 4-(methylamino)benzoate (PMAB) anions, and coordinated by one nicotinamide and one water molecule; a carboxylate O atom from the adjacent PMAB anion bridges to the Cd atom, completing the irregular seven-coordination geometry. In the crystal, intermolecular O—H...O, N—H...O and C—H...O hydrogen bonds link the molecules into a three-dimensional network. π–π contacts between the pyridine rings [centroid–centroid distance = 3.965 (1) Å] may further stabilize the structure. A weak C—H...π interaction also occurs.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810046258
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