{(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate

{(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate

In title complex, [Co(C28H22N2O2)(C5H5N)2]ClO4·1.5H2O, the CoIII ion is in a slightly distorted octahedral coordination environment with the pyridine ligands in a trans arrangement. In addition to the cation and anion, the asymmetric unit also contains three half-occupancy solvent water mol...

Full description

Bibliographic Details
Main Author: Lian-Wen Zhou
Format: Article
Language:English
Published: International Union of Crystallography 2009-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809002293
id doaj-d452b93786494809aaf6cadefc2dc0e1
record_format Article
spelling doaj-d452b93786494809aaf6cadefc2dc0e12020-11-24T21:28:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652m226m22610.1107/S1600536809002293{(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrateLian-Wen ZhouIn title complex, [Co(C28H22N2O2)(C5H5N)2]ClO4·1.5H2O, the CoIII ion is in a slightly distorted octahedral coordination environment with the pyridine ligands in a trans arrangement. In addition to the cation and anion, the asymmetric unit also contains three half-occupancy solvent water molecules and all components are connected via intermolecular O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536809002293
collection DOAJ
language English
format Article
sources DOAJ
author Lian-Wen Zhou
spellingShingle Lian-Wen Zhou
{(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate
Acta Crystallographica Section E
author_facet Lian-Wen Zhou
author_sort Lian-Wen Zhou
title {(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate
title_short {(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate
title_full {(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate
title_fullStr {(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate
title_full_unstemmed {(+)-(1R,2R)-1,2-Diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(III) perchlorate sesquihydrate
title_sort {(+)-(1r,2r)-1,2-diphenyl-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}dipyridinecobalt(iii) perchlorate sesquihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-02-01
description In title complex, [Co(C28H22N2O2)(C5H5N)2]ClO4·1.5H2O, the CoIII ion is in a slightly distorted octahedral coordination environment with the pyridine ligands in a trans arrangement. In addition to the cation and anion, the asymmetric unit also contains three half-occupancy solvent water molecules and all components are connected via intermolecular O—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809002293
work_keys_str_mv AT lianwenzhou 1r2r12diphenyl228242ethane12diylbisnitrilomethylidynediphenolatodipyridinecobaltiiiperchloratesesquihydrate
_version_ 1725968890164412416

Similar Items