Synthesis and Structural Study of Some Pyrimidinium Hexafluoridosilicates
The synthesis and spectroscopic characterization of some pyrimidinium hexafluoridosilicate salts with the formula (RH)2[SiF]6 (where R = 2-aminopyrimidine (1), cytosine (2) and 5-cyanocytosine (3)) is obtained in the reaction of SiO2 with hydrofluoric acid solution and subsequent addition of 2-amino...
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| Format: | Article |
| Language: | English |
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Slovenian Chemical Society
2015-01-01
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| Series: | Acta Chimica Slovenica |
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| Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/1069 |
| Summary: | The synthesis and spectroscopic characterization of some pyrimidinium hexafluoridosilicate salts with the formula (RH)2[SiF]6 (where R = 2-aminopyrimidine (1), cytosine (2) and 5-cyanocytosine (3)) is obtained in the reaction of SiO2 with hydrofluoric acid solution and subsequent addition of 2-aminopyrimidine, cytosine or 4-amino-2-chloropyrimidine-5-carbonitrile. The crystal structures of 1 and 3 have been determined by single-crystal X‒ray diffraction analysis. The combination of N‒H···F hydrogen bonds along with π‒π interactions between aromatic rings resulted in supramolecular architecture of cations and anions in the solid state. |
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| ISSN: | 1318-0207 1580-3155 |