(+)-{1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane-κ2P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate

(+)-{1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane-κ2P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate

The title compound, [Rh(C8H12)(C14H28P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bisphosphine ligand and a bidentate η2,η2-coordinated cycloocta-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I...

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Main Authors: Stefan Schulz, Hans-Joachim Drexler, Detlef Heller
Format: Article
Language:English
Published: International Union of Crystallography 2010-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810019859
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spelling doaj-d3660da03d314ab9ac3141ff0849d9482020-11-25T00:28:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m721m72210.1107/S1600536810019859(+)-{1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane-κ2P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborateStefan SchulzHans-Joachim DrexlerDetlef HellerThe title compound, [Rh(C8H12)(C14H28P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bisphosphine ligand and a bidentate η2,η2-coordinated cycloocta-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom. There are three molecules in the asymmetric unit and intramolecular P—Rh—P bite angles of 82.78 (5), 82.97 (6) and 83.09 (5)° are observed. The dihedral angles between the P—Rh—P and the X—Rh—X planes (X is the centroid of a double bond) are 14.7 (1), 14.8 (1) and 15.3 (1)°. The structure exhibits disorder of one cyclooctadiene ligand as well as one BF4 anion. http://scripts.iucr.org/cgi-bin/paper?S1600536810019859
collection DOAJ
language English
format Article
sources DOAJ
author Stefan Schulz
Hans-Joachim Drexler
Detlef Heller
spellingShingle Stefan Schulz
Hans-Joachim Drexler
Detlef Heller
(+)-{1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane-κ2P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate
Acta Crystallographica Section E
author_facet Stefan Schulz
Hans-Joachim Drexler
Detlef Heller
author_sort Stefan Schulz
title (+)-{1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane-κ2P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate
title_short (+)-{1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane-κ2P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate
title_full (+)-{1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane-κ2P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate
title_fullStr (+)-{1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane-κ2P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate
title_full_unstemmed (+)-{1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane-κ2P,P′}(η4-cycloocta-1,5-diene)rhodium(I) tetrafluoridoborate
title_sort (+)-{1,2-bis[(2r,5r)-2,5-dimethylphospholan-1-yl]ethane-κ2p,p′}(η4-cycloocta-1,5-diene)rhodium(i) tetrafluoridoborate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-06-01
description The title compound, [Rh(C8H12)(C14H28P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bisphosphine ligand and a bidentate η2,η2-coordinated cycloocta-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom. There are three molecules in the asymmetric unit and intramolecular P—Rh—P bite angles of 82.78 (5), 82.97 (6) and 83.09 (5)° are observed. The dihedral angles between the P—Rh—P and the X—Rh—X planes (X is the centroid of a double bond) are 14.7 (1), 14.8 (1) and 15.3 (1)°. The structure exhibits disorder of one cyclooctadiene ligand as well as one BF4 anion.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810019859
work_keys_str_mv AT stefanschulz 12bis2r5r25dimethylphospholan1ylethaneamp9542ppamp8242amp9514cycloocta15dienerhodiumitetrafluoridoborate
AT hansjoachimdrexler 12bis2r5r25dimethylphospholan1ylethaneamp9542ppamp8242amp9514cycloocta15dienerhodiumitetrafluoridoborate
AT detlefheller 12bis2r5r25dimethylphospholan1ylethaneamp9542ppamp8242amp9514cycloocta15dienerhodiumitetrafluoridoborate
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