Effects of the variation of diffusion coefficients in the potentiometric stripping analysis
Abstract A simple steady state model of potentiometric stripping analysis and its derivative mode that are influenced by the film of adsorbed substance that hinders the diffusion of oxidant and metal ions is developed. The dependence of stripping time and the maximum in the derivative mode on the de...
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Online Access: | https://doi.org/10.1002/elsa.202000013 |
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doaj-d33fe199587e48f796bc2d5bb838b3d62021-05-18T06:03:08ZengWiley-VCHElectrochemical Science Advances2698-59772021-05-0112n/an/a10.1002/elsa.202000013Effects of the variation of diffusion coefficients in the potentiometric stripping analysisMilivoj Lovrić0Divkovićeva 13 Zagreb CroatiaAbstract A simple steady state model of potentiometric stripping analysis and its derivative mode that are influenced by the film of adsorbed substance that hinders the diffusion of oxidant and metal ions is developed. The dependence of stripping time and the maximum in the derivative mode on the degree of inhibition is calculated. The responses are enhanced if the flux of oxidant is diminished.https://doi.org/10.1002/elsa.202000013chronopotentiometrydiffusion coefficientsmodel calculationpotentiometric stripping analysissignal enhancement |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Milivoj Lovrić |
spellingShingle |
Milivoj Lovrić Effects of the variation of diffusion coefficients in the potentiometric stripping analysis Electrochemical Science Advances chronopotentiometry diffusion coefficients model calculation potentiometric stripping analysis signal enhancement |
author_facet |
Milivoj Lovrić |
author_sort |
Milivoj Lovrić |
title |
Effects of the variation of diffusion coefficients in the potentiometric stripping analysis |
title_short |
Effects of the variation of diffusion coefficients in the potentiometric stripping analysis |
title_full |
Effects of the variation of diffusion coefficients in the potentiometric stripping analysis |
title_fullStr |
Effects of the variation of diffusion coefficients in the potentiometric stripping analysis |
title_full_unstemmed |
Effects of the variation of diffusion coefficients in the potentiometric stripping analysis |
title_sort |
effects of the variation of diffusion coefficients in the potentiometric stripping analysis |
publisher |
Wiley-VCH |
series |
Electrochemical Science Advances |
issn |
2698-5977 |
publishDate |
2021-05-01 |
description |
Abstract A simple steady state model of potentiometric stripping analysis and its derivative mode that are influenced by the film of adsorbed substance that hinders the diffusion of oxidant and metal ions is developed. The dependence of stripping time and the maximum in the derivative mode on the degree of inhibition is calculated. The responses are enhanced if the flux of oxidant is diminished. |
topic |
chronopotentiometry diffusion coefficients model calculation potentiometric stripping analysis signal enhancement |
url |
https://doi.org/10.1002/elsa.202000013 |
work_keys_str_mv |
AT milivojlovric effectsofthevariationofdiffusioncoefficientsinthepotentiometricstrippinganalysis |
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1721437682604703744 |