Effects of the variation of diffusion coefficients in the potentiometric stripping analysis

Abstract A simple steady state model of potentiometric stripping analysis and its derivative mode that are influenced by the film of adsorbed substance that hinders the diffusion of oxidant and metal ions is developed. The dependence of stripping time and the maximum in the derivative mode on the de...

Full description

Bibliographic Details
Main Author: Milivoj Lovrić
Format: Article
Language:English
Published: Wiley-VCH 2021-05-01
Series:Electrochemical Science Advances
Subjects:
Online Access:https://doi.org/10.1002/elsa.202000013
id doaj-d33fe199587e48f796bc2d5bb838b3d6
record_format Article
spelling doaj-d33fe199587e48f796bc2d5bb838b3d62021-05-18T06:03:08ZengWiley-VCHElectrochemical Science Advances2698-59772021-05-0112n/an/a10.1002/elsa.202000013Effects of the variation of diffusion coefficients in the potentiometric stripping analysisMilivoj Lovrić0Divkovićeva 13 Zagreb CroatiaAbstract A simple steady state model of potentiometric stripping analysis and its derivative mode that are influenced by the film of adsorbed substance that hinders the diffusion of oxidant and metal ions is developed. The dependence of stripping time and the maximum in the derivative mode on the degree of inhibition is calculated. The responses are enhanced if the flux of oxidant is diminished.https://doi.org/10.1002/elsa.202000013chronopotentiometrydiffusion coefficientsmodel calculationpotentiometric stripping analysissignal enhancement
collection DOAJ
language English
format Article
sources DOAJ
author Milivoj Lovrić
spellingShingle Milivoj Lovrić
Effects of the variation of diffusion coefficients in the potentiometric stripping analysis
Electrochemical Science Advances
chronopotentiometry
diffusion coefficients
model calculation
potentiometric stripping analysis
signal enhancement
author_facet Milivoj Lovrić
author_sort Milivoj Lovrić
title Effects of the variation of diffusion coefficients in the potentiometric stripping analysis
title_short Effects of the variation of diffusion coefficients in the potentiometric stripping analysis
title_full Effects of the variation of diffusion coefficients in the potentiometric stripping analysis
title_fullStr Effects of the variation of diffusion coefficients in the potentiometric stripping analysis
title_full_unstemmed Effects of the variation of diffusion coefficients in the potentiometric stripping analysis
title_sort effects of the variation of diffusion coefficients in the potentiometric stripping analysis
publisher Wiley-VCH
series Electrochemical Science Advances
issn 2698-5977
publishDate 2021-05-01
description Abstract A simple steady state model of potentiometric stripping analysis and its derivative mode that are influenced by the film of adsorbed substance that hinders the diffusion of oxidant and metal ions is developed. The dependence of stripping time and the maximum in the derivative mode on the degree of inhibition is calculated. The responses are enhanced if the flux of oxidant is diminished.
topic chronopotentiometry
diffusion coefficients
model calculation
potentiometric stripping analysis
signal enhancement
url https://doi.org/10.1002/elsa.202000013
work_keys_str_mv AT milivojlovric effectsofthevariationofdiffusioncoefficientsinthepotentiometricstrippinganalysis
_version_ 1721437682604703744