Benzene-1,3-diammonium bis(pyridine-2,6-dicarboxylato)nickelate(II) pentahydrate

In the title compound, (C6H10N2)[Ni(C7H3NO4)2]·5H2O, the NiII ion is six-coordinated by two N and four O atoms from two pyridine-2,6-dicarboxylate ligands in a distorted octahedral fashion. The crystal packing is stabilized by intermolecular O—H...O and N—H.....

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Bibliographic Details
Main Authors: Hoda Pasdar, Saghi Sadat Kashani, Hossein Aghabozorg, Behrouz Notash
Format: Article
Language:English
Published: International Union of Crystallography 2011-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810054371
Description
Summary:In the title compound, (C6H10N2)[Ni(C7H3NO4)2]·5H2O, the NiII ion is six-coordinated by two N and four O atoms from two pyridine-2,6-dicarboxylate ligands in a distorted octahedral fashion. The crystal packing is stabilized by intermolecular O—H...O and N—H...O and weak C—H...O hydrogen bonds and π–π interactions [centroid–centroid distances = 3.4669 (19) and 3.764 (2) Å].
ISSN:1600-5368