Synthesis and photo-physical properties of fluorescent 1,3,5-triazine styryl derivatives

<p>Abstract</p> <p>Background</p> <p>Organic fluorophore contains well-defined D-π-A (Donor-π system-Acceptor) push-pull system have wide application in the field of NLO, OLED and high tech application. Electron donor diphenyl, triphenyl and carbazole conjugated with el...

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Bibliographic Details
Main Authors: Padalkar Vikas S, Patil Vikas S, Sekar N
Format: Article
Language:English
Published: BMC 2011-12-01
Series:Chemistry Central Journal
Online Access:http://journal.chemistrycentral.com/content/5/1/77
Description
Summary:<p>Abstract</p> <p>Background</p> <p>Organic fluorophore contains well-defined D-π-A (Donor-π system-Acceptor) push-pull system have wide application in the field of NLO, OLED and high tech application. Electron donor diphenyl, triphenyl and carbazole conjugated with electron acceptor terminal through π-system were reported recently for high-tech applications. <it>N,N</it>-Dialkyl substituted 1,3,5-triazine also acts as donor keeping this idea in mind we developed D-π-A styryl dyes.</p> <p>Results</p> <p>Novel "Y"-shaped acceptor-<it>π</it>-donor-<it>π</it>-acceptor type of compounds were synthesized from 4,4'-((6-(4-(diethylamino)phenyl)-1,3,5-triazine-2,4diyl)bis(oxy)) dibenzaldehyde (DIPOD) as electron donors and different active methylene compounds as electron acceptors by conventional Knoevenagel condensation reaction. Their photophysical and thermal properties were investigated.</p> <p>Conclusion</p> <p>It was found that the strong electron acceptor-donor chromophoric system of these compounds showed high Stoke's shift and excellent thermal stability. Compounds showed positive solvatofluorism behavior from nonpolar to polar solvent. All compounds have good thermal stability.</p>
ISSN:1752-153X