Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)]

Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)]

In the title complex, [Mn3(CH3CO2)6(C2H6SO)2]n, the MnII ions exhibit similar MnO6 octahedral coordination geometries but with different coordination environments. One type of MnII ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axi...

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Main Authors: Chong-Qing Wan, Nai-You Xiao, Zi-Jia Wang
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810042558
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spelling doaj-d1ec44cb4d40407a87905fb1d776bb462020-11-25T01:56:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1478m147810.1107/S1600536810042558Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)]Chong-Qing WanNai-You XiaoZi-Jia WangIn the title complex, [Mn3(CH3CO2)6(C2H6SO)2]n, the MnII ions exhibit similar MnO6 octahedral coordination geometries but with different coordination environments. One type of MnII ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axis and is coordinated by six O atoms from three symmetry-related acetate ions. The acetate anions exhibit three independent bridging modes, which flexibly bridge the MnII ions along the c-axis direction, forming an infinite chain structure; the chains are further interconnected through weak C—H...O and C—H...S hydrogen-bonding interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536810042558
collection DOAJ
language English
format Article
sources DOAJ
author Chong-Qing Wan
Nai-You Xiao
Zi-Jia Wang
spellingShingle Chong-Qing Wan
Nai-You Xiao
Zi-Jia Wang
Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)]
Acta Crystallographica Section E
author_facet Chong-Qing Wan
Nai-You Xiao
Zi-Jia Wang
author_sort Chong-Qing Wan
title Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)]
title_short Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)]
title_full Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)]
title_fullStr Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)]
title_full_unstemmed Poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(II)]
title_sort poly[hexa-μ-acetato-bis(dimethyl sulfoxide)trimanganese(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-11-01
description In the title complex, [Mn3(CH3CO2)6(C2H6SO)2]n, the MnII ions exhibit similar MnO6 octahedral coordination geometries but with different coordination environments. One type of MnII ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axis and is coordinated by six O atoms from three symmetry-related acetate ions. The acetate anions exhibit three independent bridging modes, which flexibly bridge the MnII ions along the c-axis direction, forming an infinite chain structure; the chains are further interconnected through weak C—H...O and C—H...S hydrogen-bonding interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810042558
work_keys_str_mv AT chongqingwan polyhexaamp956acetatobisdimethylsulfoxidetrimanganeseii
AT naiyouxiao polyhexaamp956acetatobisdimethylsulfoxidetrimanganeseii
AT zijiawang polyhexaamp956acetatobisdimethylsulfoxidetrimanganeseii
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