Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism

Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism

The current industrial ammonia synthesis relies on the Haber-Bosch process that is limited by the Brønsted–Evans–Polanyi relation. Here, the authors propose a new strategy that an anchored Fe3 on θ-Al2O3(010) surface serves as a heterogeneous single cluster catalyst for ammonia synthesis from first-...

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Main Authors: Jin-Cheng Liu, Xue-Lu Ma, Yong Li, Yang-Gang Wang, Hai Xiao, Jun Li
Format: Article
Language:English
Published: Nature Publishing Group 2018-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-018-03795-8
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spelling doaj-d1d7475fdcac4f8aae74d934a892b0712021-05-11T10:11:52ZengNature Publishing GroupNature Communications2041-17232018-04-01911910.1038/s41467-018-03795-8Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanismJin-Cheng Liu0Xue-Lu Ma1Yong Li2Yang-Gang Wang3Hai Xiao4Jun Li5Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua UniversityDepartment of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua UniversityDepartment of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua UniversityDepartment of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua UniversityDepartment of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua UniversityDepartment of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua UniversityThe current industrial ammonia synthesis relies on the Haber-Bosch process that is limited by the Brønsted–Evans–Polanyi relation. Here, the authors propose a new strategy that an anchored Fe3 on θ-Al2O3(010) surface serves as a heterogeneous single cluster catalyst for ammonia synthesis from first-principles calculations and microkinetic analysis.https://doi.org/10.1038/s41467-018-03795-8
collection DOAJ
language English
format Article
sources DOAJ
author Jin-Cheng Liu
Xue-Lu Ma
Yong Li
Yang-Gang Wang
Hai Xiao
Jun Li
spellingShingle Jin-Cheng Liu
Xue-Lu Ma
Yong Li
Yang-Gang Wang
Hai Xiao
Jun Li
Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism
Nature Communications
author_facet Jin-Cheng Liu
Xue-Lu Ma
Yong Li
Yang-Gang Wang
Hai Xiao
Jun Li
author_sort Jin-Cheng Liu
title Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism
title_short Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism
title_full Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism
title_fullStr Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism
title_full_unstemmed Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism
title_sort heterogeneous fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2018-04-01
description The current industrial ammonia synthesis relies on the Haber-Bosch process that is limited by the Brønsted–Evans–Polanyi relation. Here, the authors propose a new strategy that an anchored Fe3 on θ-Al2O3(010) surface serves as a heterogeneous single cluster catalyst for ammonia synthesis from first-principles calculations and microkinetic analysis.
url https://doi.org/10.1038/s41467-018-03795-8
work_keys_str_mv AT jinchengliu heterogeneousfe3singleclustercatalystforammoniasynthesisviaanassociativemechanism
AT xueluma heterogeneousfe3singleclustercatalystforammoniasynthesisviaanassociativemechanism
AT yongli heterogeneousfe3singleclustercatalystforammoniasynthesisviaanassociativemechanism
AT yanggangwang heterogeneousfe3singleclustercatalystforammoniasynthesisviaanassociativemechanism
AT haixiao heterogeneousfe3singleclustercatalystforammoniasynthesisviaanassociativemechanism
AT junli heterogeneousfe3singleclustercatalystforammoniasynthesisviaanassociativemechanism
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