(Acetylacetonato)dibromido[2,2-diphenylhydrazin-1-ido(1−)][2,2-diphenylhydrazin-1-ido(2−)]molybdenum(VI)

(Acetylacetonato)dibromido[2,2-diphenylhydrazin-1-ido(1−)][2,2-diphenylhydrazin-1-ido(2−)]molybdenum(VI)

In the title compound, [MoBr2(C12H11N2)(C12H10N2)(C5H7O2)], the MoVI atom is six-coordinated in a distorted octahedral geometry by two N atoms from the diphenylhydrazide(1−) and diphenylhydrazide(2−) ligands, two O atoms from a bidentate acetylacetonate ligand and two Br&...

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Main Authors: Carlos Bustos, Luis Alvarez-Thon, Andrés Ibañez, Christian Sánchez
Format: Article
Language:English
Published: International Union of Crystallography 2011-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811015881
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spelling doaj-d1d329a42df143d09696415d871d6ae22020-11-25T02:19:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m675m67610.1107/S1600536811015881(Acetylacetonato)dibromido[2,2-diphenylhydrazin-1-ido(1−)][2,2-diphenylhydrazin-1-ido(2−)]molybdenum(VI)Carlos BustosLuis Alvarez-ThonAndrés IbañezChristian SánchezIn the title compound, [MoBr2(C12H11N2)(C12H10N2)(C5H7O2)], the MoVI atom is six-coordinated in a distorted octahedral geometry by two N atoms from the diphenylhydrazide(1−) and diphenylhydrazide(2−) ligands, two O atoms from a bidentate acetylacetonate ligand and two Br− ions. The molecules form an inversion dimer via a pair of weak C—H...O hydrogen bonds and a π–π stacking interaction with a centroid–centroid distance of 3.7401 (12) Å. Weak intramolecular C—H...Br interactions and an intramolecular π–π stacking interaction with a centroid–centroid distance of 3.8118 (15) Å are also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536811015881
collection DOAJ
language English
format Article
sources DOAJ
author Carlos Bustos
Luis Alvarez-Thon
Andrés Ibañez
Christian Sánchez
spellingShingle Carlos Bustos
Luis Alvarez-Thon
Andrés Ibañez
Christian Sánchez
(Acetylacetonato)dibromido[2,2-diphenylhydrazin-1-ido(1−)][2,2-diphenylhydrazin-1-ido(2−)]molybdenum(VI)
Acta Crystallographica Section E
author_facet Carlos Bustos
Luis Alvarez-Thon
Andrés Ibañez
Christian Sánchez
author_sort Carlos Bustos
title (Acetylacetonato)dibromido[2,2-diphenylhydrazin-1-ido(1−)][2,2-diphenylhydrazin-1-ido(2−)]molybdenum(VI)
title_short (Acetylacetonato)dibromido[2,2-diphenylhydrazin-1-ido(1−)][2,2-diphenylhydrazin-1-ido(2−)]molybdenum(VI)
title_full (Acetylacetonato)dibromido[2,2-diphenylhydrazin-1-ido(1−)][2,2-diphenylhydrazin-1-ido(2−)]molybdenum(VI)
title_fullStr (Acetylacetonato)dibromido[2,2-diphenylhydrazin-1-ido(1−)][2,2-diphenylhydrazin-1-ido(2−)]molybdenum(VI)
title_full_unstemmed (Acetylacetonato)dibromido[2,2-diphenylhydrazin-1-ido(1−)][2,2-diphenylhydrazin-1-ido(2−)]molybdenum(VI)
title_sort (acetylacetonato)dibromido[2,2-diphenylhydrazin-1-ido(1−)][2,2-diphenylhydrazin-1-ido(2−)]molybdenum(vi)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-06-01
description In the title compound, [MoBr2(C12H11N2)(C12H10N2)(C5H7O2)], the MoVI atom is six-coordinated in a distorted octahedral geometry by two N atoms from the diphenylhydrazide(1−) and diphenylhydrazide(2−) ligands, two O atoms from a bidentate acetylacetonate ligand and two Br− ions. The molecules form an inversion dimer via a pair of weak C—H...O hydrogen bonds and a π–π stacking interaction with a centroid–centroid distance of 3.7401 (12) Å. Weak intramolecular C—H...Br interactions and an intramolecular π–π stacking interaction with a centroid–centroid distance of 3.8118 (15) Å are also observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811015881
work_keys_str_mv AT carlosbustos acetylacetonatodibromido22diphenylhydrazin1ido1amp872222diphenylhydrazin1ido2amp8722molybdenumvi
AT luisalvarezthon acetylacetonatodibromido22diphenylhydrazin1ido1amp872222diphenylhydrazin1ido2amp8722molybdenumvi
AT andramp233sibaamp241ez acetylacetonatodibromido22diphenylhydrazin1ido1amp872222diphenylhydrazin1ido2amp8722molybdenumvi
AT christiansamp225nchez acetylacetonatodibromido22diphenylhydrazin1ido1amp872222diphenylhydrazin1ido2amp8722molybdenumvi
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