(Acetylacetonato)dibromido[2,2-diphenylhydrazin-1-ido(1−)][2,2-diphenylhydrazin-1-ido(2−)]molybdenum(VI)
In the title compound, [MoBr2(C12H11N2)(C12H10N2)(C5H7O2)], the MoVI atom is six-coordinated in a distorted octahedral geometry by two N atoms from the diphenylhydrazide(1−) and diphenylhydrazide(2−) ligands, two O atoms from a bidentate acetylacetonate ligand and two Br&...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811015881 |
| Summary: | In the title compound, [MoBr2(C12H11N2)(C12H10N2)(C5H7O2)], the MoVI atom is six-coordinated in a distorted octahedral geometry by two N atoms from the diphenylhydrazide(1−) and diphenylhydrazide(2−) ligands, two O atoms from a bidentate acetylacetonate ligand and two Br− ions. The molecules form an inversion dimer via a pair of weak C—H...O hydrogen bonds and a π–π stacking interaction with a centroid–centroid distance of 3.7401 (12) Å. Weak intramolecular C—H...Br interactions and an intramolecular π–π stacking interaction with a centroid–centroid distance of 3.8118 (15) Å are also observed. |
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| ISSN: | 1600-5368 |