trans-Dichloridobis(pyridazine-κN)palladium(II)
The title compound, [PdCl2(C4H4N2)2], contains two crystallographically unique complexes; the PdII atom lies on an inversion center in both cases. The two pyridazine units bonded to the PdII atom are thus coplanar although dihedral angles within each complex are different. In one complex, the angle...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2014-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813032716 |
| Summary: | The title compound, [PdCl2(C4H4N2)2], contains two crystallographically unique complexes; the PdII atom lies on an inversion center in both cases. The two pyridazine units bonded to the PdII atom are thus coplanar although dihedral angles within each complex are different. In one complex, the angle between the ring plane and Pd—Cl bond is almost perpendicular [89.4 (1)°], while the other is tilted with an angle of 60.0 (1)°. In the crystal, weak C...H—N hydrogen bonds and C...H—Cl interactions connect the two independent complex molecules. |
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| ISSN: | 1600-5368 |