(1-Acetylthiourea-κS)bromidobis(triphenylphosphane-κP)silver(I)
In the title complex, [AgBr(C3H6N2OS)(C18H15P)2], the AgI ion is in a distorted tetrahedral geometry coordinated by two P atoms from two triphenylphosphane ligands, one S atom of an acetylthiourea ligand and one bromide ligand. There are intramolecular N—H...Br and N—H......
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| Format: | Article |
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International Union of Crystallography
2012-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812045199 |
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doaj-d158eb7b5b4e40168ee11bc329b21f482020-11-25T01:27:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1506m150710.1107/S1600536812045199(1-Acetylthiourea-κS)bromidobis(triphenylphosphane-κP)silver(I)Chaveng PakawatchaiPiyapong JantaramasJedsada MokhagulRuthairat NimthongIn the title complex, [AgBr(C3H6N2OS)(C18H15P)2], the AgI ion is in a distorted tetrahedral geometry coordinated by two P atoms from two triphenylphosphane ligands, one S atom of an acetylthiourea ligand and one bromide ligand. There are intramolecular N—H...Br and N—H...O hydrogen bonds present. In the crystal, pairs of N—H...S hydrogen bonds involving thiourea groups form inversion dimers. In addition, moleclues pack to give sixfold phenyl embraces with an intermolecular P...P distance of 6.4586 (17) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536812045199 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Chaveng Pakawatchai Piyapong Jantaramas Jedsada Mokhagul Ruthairat Nimthong |
| spellingShingle |
Chaveng Pakawatchai Piyapong Jantaramas Jedsada Mokhagul Ruthairat Nimthong (1-Acetylthiourea-κS)bromidobis(triphenylphosphane-κP)silver(I) Acta Crystallographica Section E |
| author_facet |
Chaveng Pakawatchai Piyapong Jantaramas Jedsada Mokhagul Ruthairat Nimthong |
| author_sort |
Chaveng Pakawatchai |
| title |
(1-Acetylthiourea-κS)bromidobis(triphenylphosphane-κP)silver(I) |
| title_short |
(1-Acetylthiourea-κS)bromidobis(triphenylphosphane-κP)silver(I) |
| title_full |
(1-Acetylthiourea-κS)bromidobis(triphenylphosphane-κP)silver(I) |
| title_fullStr |
(1-Acetylthiourea-κS)bromidobis(triphenylphosphane-κP)silver(I) |
| title_full_unstemmed |
(1-Acetylthiourea-κS)bromidobis(triphenylphosphane-κP)silver(I) |
| title_sort |
(1-acetylthiourea-κs)bromidobis(triphenylphosphane-κp)silver(i) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-12-01 |
| description |
In the title complex, [AgBr(C3H6N2OS)(C18H15P)2], the AgI ion is in a distorted tetrahedral geometry coordinated by two P atoms from two triphenylphosphane ligands, one S atom of an acetylthiourea ligand and one bromide ligand. There are intramolecular N—H...Br and N—H...O hydrogen bonds present. In the crystal, pairs of N—H...S hydrogen bonds involving thiourea groups form inversion dimers. In addition, moleclues pack to give sixfold phenyl embraces with an intermolecular P...P distance of 6.4586 (17) Å. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812045199 |
| work_keys_str_mv |
AT chavengpakawatchai 1acetylthioureaamp954sbromidobistriphenylphosphaneamp954psilveri AT piyapongjantaramas 1acetylthioureaamp954sbromidobistriphenylphosphaneamp954psilveri AT jedsadamokhagul 1acetylthioureaamp954sbromidobistriphenylphosphaneamp954psilveri AT ruthairatnimthong 1acetylthioureaamp954sbromidobistriphenylphosphaneamp954psilveri |
| _version_ |
1725104306972000256 |