Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)

Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)

In the title complex, [Mn(C5H7O2)2(NCS)(CH4O)], the MnIII atom has a slightly distorted octahedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetylacetonate ligands, while the axial positions are occupied by the N atom of the thi...

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Main Authors: Shuang-Ming Meng, Hai Xie, Yue-Qin Fan, Yong Guo
Format: Article
Language:English
Published: International Union of Crystallography 2008-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808031589
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spelling doaj-d149988573da49e988c64cc7d9af11dc2020-11-24T21:24:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1363m136310.1107/S1600536808031589Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)Shuang-Ming MengHai XieYue-Qin FanYong GuoIn the title complex, [Mn(C5H7O2)2(NCS)(CH4O)], the MnIII atom has a slightly distorted octahedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetylacetonate ligands, while the axial positions are occupied by the N atom of the thiocyanate anion and the O atom of the methanol molecule. In the crystal structure, complex molecules are linked by an intermolecular O—H...S hydrogen bond, forming a chain running along [101].http://scripts.iucr.org/cgi-bin/paper?S1600536808031589
collection DOAJ
language English
format Article
sources DOAJ
author Shuang-Ming Meng
Hai Xie
Yue-Qin Fan
Yong Guo
spellingShingle Shuang-Ming Meng
Hai Xie
Yue-Qin Fan
Yong Guo
Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)
Acta Crystallographica Section E
author_facet Shuang-Ming Meng
Hai Xie
Yue-Qin Fan
Yong Guo
author_sort Shuang-Ming Meng
title Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)
title_short Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)
title_full Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)
title_fullStr Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)
title_full_unstemmed Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)
title_sort bis(acetylacetonato-κ2o,o′)(methanol-κo)(thiocyanato-κn)manganese(iii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-11-01
description In the title complex, [Mn(C5H7O2)2(NCS)(CH4O)], the MnIII atom has a slightly distorted octahedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetylacetonate ligands, while the axial positions are occupied by the N atom of the thiocyanate anion and the O atom of the methanol molecule. In the crystal structure, complex molecules are linked by an intermolecular O—H...S hydrogen bond, forming a chain running along [101].
url http://scripts.iucr.org/cgi-bin/paper?S1600536808031589
work_keys_str_mv AT shuangmingmeng bisacetylacetonato9542oo8242methanol954othiocyanato954nmanganeseiii
AT haixie bisacetylacetonato9542oo8242methanol954othiocyanato954nmanganeseiii
AT yueqinfan bisacetylacetonato9542oo8242methanol954othiocyanato954nmanganeseiii
AT yongguo bisacetylacetonato9542oo8242methanol954othiocyanato954nmanganeseiii
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