Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)

Bis(acetylacetonato-κ2O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)

In the title complex, [Mn(C5H7O2)2(NCS)(CH4O)], the MnIII atom has a slightly distorted octahedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetylacetonate ligands, while the axial positions are occupied by the N atom of the thi...

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Bibliographic Details
Main Authors: Shuang-Ming Meng, Hai Xie, Yue-Qin Fan, Yong Guo
Format: Article
Language:English
Published: International Union of Crystallography 2008-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808031589
Description
Summary:In the title complex, [Mn(C5H7O2)2(NCS)(CH4O)], the MnIII atom has a slightly distorted octahedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetylacetonate ligands, while the axial positions are occupied by the N atom of the thiocyanate anion and the O atom of the methanol molecule. In the crystal structure, complex molecules are linked by an intermolecular O—H...S hydrogen bond, forming a chain running along [101].
ISSN:1600-5368

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