Relations between angular and Cartesian orientational expansions

Orientational expansions, which are widely used in natural sciences, exist in angular and Cartesian forms. Although these expansions are orderwise equivalent, it is difficult to relate them in practice. In this article, both types of expansions and their relations are explained in detail. We give ex...

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Bibliographic Details
Main Authors: Michael te Vrugt, Raphael Wittkowski
Format: Article
Language:English
Published: AIP Publishing LLC 2020-03-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.5141367
Description
Summary:Orientational expansions, which are widely used in natural sciences, exist in angular and Cartesian forms. Although these expansions are orderwise equivalent, it is difficult to relate them in practice. In this article, both types of expansions and their relations are explained in detail. We give explicit formulas for the conversion between angular and Cartesian expansion coefficients for functions depending on one, two, and three angles in two and three spatial dimensions. These formulas are useful, e.g., for comparing theoretical and experimental results in liquid crystal physics. The application of the expansions in the definition of orientational order parameters is also discussed.
ISSN:2158-3226