Bis(2,2′-bipyridine-κ2N,N′)(croconato-κ2O,O′)nickel(II)

Bis(2,2′-bipyridine-κ2N,N′)(croconato-κ2O,O′)nickel(II)

The title compound, [Ni(C5O5)(C10H8N2)2], lies across a crystallographic twofold axis, around which two 2,2′-bipyridine (2,2′-bipy) ligands are arranged in a propeller manner. The local geometry of the NiN4O2 coordination core basically adopts an octahedral geometry. The molecula...

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Bibliographic Details
Main Authors: Hong-Feng Chen, Qi Fang, Wen-Tao Yu
Format: Article
Language:English
Published: International Union of Crystallography 2008-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808033771
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spelling doaj-d0e5958f7c0a4f25b2a2b2d5ff3d99902020-11-24T20:56:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1459m145910.1107/S1600536808033771Bis(2,2′-bipyridine-κ2N,N′)(croconato-κ2O,O′)nickel(II)Hong-Feng ChenQi FangWen-Tao YuThe title compound, [Ni(C5O5)(C10H8N2)2], lies across a crystallographic twofold axis, around which two 2,2′-bipyridine (2,2′-bipy) ligands are arranged in a propeller manner. The local geometry of the NiN4O2 coordination core basically adopts an octahedral geometry. The molecular twofold axis is along the direction of the molecular dipole moment, and the complex is packed with its dipole moment alternately along the +b and −b directions. The crystal structure is stabilized by intermolecular C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536808033771
collection DOAJ
language English
format Article
sources DOAJ
author Hong-Feng Chen
Qi Fang
Wen-Tao Yu
spellingShingle Hong-Feng Chen
Qi Fang
Wen-Tao Yu
Bis(2,2′-bipyridine-κ2N,N′)(croconato-κ2O,O′)nickel(II)
Acta Crystallographica Section E
author_facet Hong-Feng Chen
Qi Fang
Wen-Tao Yu
author_sort Hong-Feng Chen
title Bis(2,2′-bipyridine-κ2N,N′)(croconato-κ2O,O′)nickel(II)
title_short Bis(2,2′-bipyridine-κ2N,N′)(croconato-κ2O,O′)nickel(II)
title_full Bis(2,2′-bipyridine-κ2N,N′)(croconato-κ2O,O′)nickel(II)
title_fullStr Bis(2,2′-bipyridine-κ2N,N′)(croconato-κ2O,O′)nickel(II)
title_full_unstemmed Bis(2,2′-bipyridine-κ2N,N′)(croconato-κ2O,O′)nickel(II)
title_sort bis(2,2′-bipyridine-κ2n,n′)(croconato-κ2o,o′)nickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-11-01
description The title compound, [Ni(C5O5)(C10H8N2)2], lies across a crystallographic twofold axis, around which two 2,2′-bipyridine (2,2′-bipy) ligands are arranged in a propeller manner. The local geometry of the NiN4O2 coordination core basically adopts an octahedral geometry. The molecular twofold axis is along the direction of the molecular dipole moment, and the complex is packed with its dipole moment alternately along the +b and −b directions. The crystal structure is stabilized by intermolecular C—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808033771
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AT qifang bis228242bipyridine9542nn8242croconato9542oo8242nickelii
AT wentaoyu bis228242bipyridine9542nn8242croconato9542oo8242nickelii
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